NEET · Chemistry —

Alcohols Phenols and Ethers appeared 3 times across 1 year — 6.7% of Chemistry. This question is from Chemical Tests for Phenols.

Year 2024 Total
Questions 3 3

The functional group that can be identified through phthalein dye test is :

Solution & Explanation

Core Logic

Phthalein Dye Test: Phenol on heating with phthalic anhydride in the presence of concentrated sulphuric acid forms a colourless condensation compound called phenolphthalein. On further reaction with a base (like NaOH), it yields a deep pink (or red) coloured solution due to the formation of its sodium salt. This test is highly specific to the phenolic group.

Step 1: Final Conclusion

The functional group identified is Phenolic.

Pattern Recognition

Phthalein dye test = Phenol. Tollens'/Fehling's = Aldehyde. Lucas = Alcohols. Bicarbonate test = Carboxylic Acid.

Chapter Mix

Class 12 Chemistry: Alcohols, Phenols and Ethers Class 12 Chemistry: Practical Chemistry

Reference Study Guides

More Alcohols, Phenols and Ethers Previous-Year Questions

Q46 neet_2026_03_may_morning Preparation Of Phenols And Alcohols
Match List I with List II
List-IList-II
A. H₃C-CH(CH₃)-OH
Preparation Of Phenols And Alcohols diagram for Q46 - NEET 2026 Code 12
Displays reactant and product chemical structures for matching with their respective reagents.
(I) (i) Oleum; (ii) NaOH, Δ; (iii) H⁺
B. CH₃COOH CH₃CH₂OH(II) (i) O₂; (ii) H₂O/H⁺
C. CH₃CH₂CH₂OH CH₃-CH(OH)-CH₃(III) (i) CH₃OH, H⁺; (ii) H₂, catalyst
D.
Preparation Of Phenols And Alcohols diagram for Q46 - NEET 2026 Code 12
Displays reactant and product chemical structures for matching with their respective reagents.
(IV) (i) conc. H₂SO₄, Δ; (ii) H⁺/H₂O
Choose the correct answer from the options given below :
  • A. A-I, B-III, C-IV, D-II
  • B. A-II, B-IV, C-III, D-I
  • C. A-II, B-III, C-I, D-IV
  • D. A-II, B-III, C-IV, D-I

Solution

Core Logic

A. Cumene hydroperoxide reaction: Cumene is treated with O₂ followed by hydrolysis (H₂O/H^+) to form Phenol.

Solution for Q46 - Reaction Mechanism
Displays reactant and product chemical structures for matching with their respective reagents.

B. Reduction of Carboxylic Acid: CH₃COOH is reduced using catalysts or transformed via intermediate esters to CH₃CH₂OH. CH₃COOH [(ii) H₂, catalyst](i) CH₃OH, H^+ CH₃CH₂OH

C. Conversion of 1^° alcohol to 2^° alcohol involves Dehydration followed by Hydration: CH₃CH₂CH₂-OH [Dehydration]conc. H₂SO₄ / Δ CH₃CH=CH₂ H^+ / H₂O CH₃CH(OH)CH₃

D. Benzene sulphonic acid to Phenol:

Solution for Q46 - Reaction Mechanism
Displays reactant and product chemical structures for matching with their respective reagents.
Reagents used: (i) Oleum, (ii) NaOH, Δ, (iii) H^+.

Step 1: Final Match

A arrow II B arrow III C arrow IV D arrow I

Pattern Recognition

Standard organic conversions: Phenol from cumene requires O₂ and acid. Phenol from benzene uses oleum and NaOH fuse. Dehydration/hydration shifts OH position.

Chapter Mix

Class 12 Chemistry: Alcohols, Phenols and Ethers

Q52 neet_2026_03_may_morning Reactions of Alcohols
In the following reaction sequence, X and Z respectively are :
Reactions of Alcohols diagram for Q52 - NEET 2026 Code 12
Displays a multi-step organic conversion starting from propanol to product Z.
  • A. X = POCl₃; Z = CH₃ - CH(Br) - CH₃
  • B. X = H₃PO₃; Z = CH₃CH₂CH₂ - Br
  • C. X = H₃PO₃; Z = CH₃ - CH(Br) - CH₃
  • D. X = POCl₃; Z = CH₃CH₂CH₂ - Br

Solution

Core Logic

Step 1: Reaction of Alcohols with PCl₅ CH₃CH₂CH₂-OH + PCl₅ arrow CH₃CH₂CH₂Cl + POCl₃ + HCl Thus, the by-product X is POCl₃.

Step 2: Elimination (Dehydrohalogenation) CH₃CH₂CH₂Cl alc. KOH, Δ CH₃CH=CH₂ (Y) (Propene)

Step 3: Anti-Markovnikov Addition (Peroxide effect) CH₃CH=CH₂ HBr, (CH₃COO)₂ CH₃CH₂CH₂-Br (Z) (1-Bromopropane)

Solution for Q52 - Organic Sequence
Displays a multi-step organic conversion starting from propanol to product Z.

Step 1: Final Conclusion

Therefore, X = POCl₃ and Z = CH₃CH₂CH₂Br.

Pattern Recognition

PCl₅ yields POCl₃, whereas PCl₃ yields H₃PO₃. HBr with peroxide is Kharasch effect (Anti-Markovnikov addition), placing the Bromine on the less hindered terminal carbon.

Chapter Mix

Class 12 Chemistry: Alcohols, Phenols and Ethers Class 12 Chemistry: Haloalkanes and Haloarenes

More Alcohols, Phenols and Ethers Questions — neet_2026_03_may_morning

Practice all Alcohols, Phenols and Ethers previous-year questions →

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