| List-I | List-II |
|---|---|
| A. H₃C-CH(CH₃)-OH | (I) (i) Oleum; (ii) NaOH, Δ; (iii) H⁺ |
| B. CH₃COOH CH₃CH₂OH | (II) (i) O₂; (ii) H₂O/H⁺ |
| C. CH₃CH₂CH₂OH CH₃-CH(OH)-CH₃ | (III) (i) CH₃OH, H⁺; (ii) H₂, catalyst |
| D. | (IV) (i) conc. H₂SO₄, Δ; (ii) H⁺/H₂O |
Solution
Core Logic
A. Cumene hydroperoxide reaction: Cumene is treated with O₂ followed by hydrolysis (H₂O/H^+) to form Phenol.
B. Reduction of Carboxylic Acid: CH₃COOH is reduced using catalysts or transformed via intermediate esters to CH₃CH₂OH. CH₃COOH [(ii) H₂, catalyst](i) CH₃OH, H^+ CH₃CH₂OH
C. Conversion of 1^° alcohol to 2^° alcohol involves Dehydration followed by Hydration: CH₃CH₂CH₂-OH [Dehydration]conc. H₂SO₄ / Δ CH₃CH=CH₂ H^+ / H₂O CH₃CH(OH)CH₃
D. Benzene sulphonic acid to Phenol:
Step 1: Final Match
A arrow II B arrow III C arrow IV D arrow I
Pattern Recognition
Standard organic conversions: Phenol from cumene requires O₂ and acid. Phenol from benzene uses oleum and NaOH fuse. Dehydration/hydration shifts OH position.
Chapter Mix
Class 12 Chemistry: Alcohols, Phenols and Ethers