Solution
Related Formula
Ideal Gas Law:
n = (PV)/(RT)Conservation of moles: n₁ + n₂ = nf
Core Logic
Let the volume of the smaller vessel be V₁ = V, then the volume of the larger vessel is V₂ = 2V. Initial moles in large vessel:
n₂ = (8 × 2V)/(R × 1000) = (16V)/(1000R)Initial moles in small vessel:
n₁ = (7 × V)/(R × 500) = (14V)/(1000R)Total total initial moles:
ntotal = n₁ + n₂ = (30V)/(1000R)Step 1: Connect Vessels to Dynamic Equilibrium
When connected, the total final volume is Vf = V + 2V = 3V. The final temperature is Tf = 600 K. Using mole conservation:
(30V)/(1000R) = (Pf (3V))/(R × 600) (30)/(1000) = (3Pf)/(600) (30)/(1000) = (Pf)/(200)Pf = (30 × 200)/(1000) = 6 kPa
Pattern Recognition
Connecting chambers preserves the net mass/moles (Σ nᵢ = constant). Keep everything relative to a common volume multiplier V to easily cancel terms.
Chapter Mix
Class 11 Physics: Kinetic Theory