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Biomolecules appeared 35 times across 3 years — 4.1% of Chemistry. This question is from Hydrolysis of Sucrose.

Year 2026 2025 2024 Total
Questions 9 18 8 35

Given below are two statements: Statement I: D-(+)-glucose + D-(+)-fructose -H₂O sucrose sucrose Hydrolysis D-(+)-glucose + D-(+)-fructose Statement II: Invert sugar is formed during sucrose hydrolysis. In the light of given statements, choose the correct answer from the options given below:

Solution & Explanation

Core Logic

Statement I: Sucrose is formed by condensation of D-(+)-glucose and D-(-)-fructose (levorotatory fructose, not dextrorotatory as claimed). Hydrolysis of sucrose yields D-(+)-glucose and D-(-)-fructose. Thus, Statement I is false.

Statement II: Hydrolysis of dextrorotatory sucrose (+66.5°) yields a mixture of dextrorotatory glucose (+52.5°) and highly levorotatory fructose (-92.4°). Because the overall specific rotation of the mixture becomes levorotatory (-39.9°), the hydrolyzed mixture is called invert sugar. Thus, Statement II is true.

Pattern Recognition

Natural fructose is always levorotatory, D-(-)-fructose. Dextrorotatory fructose mentioned in Statement I is an immediate giveaway that the statement is false.

Chapter Mix

Class 12 Chemistry: Biomolecules

Reference Study Guides

More Biomolecules Previous-Year Questions — Page 3

Q jee_main_2025_02_april_morning Molar Mass Calculations
0.1~mol of the following given antiviral compound (P) will weigh × 10⁻¹~g
Antiviral nucleoside structural layout diagram for Q48
The diagram displays the full multi-cyclic skeletal structure of an antiviral nucleoside molecule featuring explicit iodine and fluorine atomic positions.
(Given : molar mass in g · mol⁻¹ H: 1, C: 12, N: 14, O: 16, F: 19, I: 127)
Numerical Answer. Answer: 372 to 372

Solution

Related Formula

Standard molecular weight calculation formula system:

Molar Mass = Σ (Atom Count × Atomic Weight) Mass = Moles × Molar Mass
Core Logic

Let's tabulate and sum up the constituent atoms based on the verified structural formula layout :

  • Counting positions meticulously yields a molecular identity formula of C₉H₁₀FIN₂O₄.
  • Calculating the total molar mass:
Mass = (9 × 12) + (10 × 1) + 19 + 127 + (2 × 14) + (4 × 16) Mass = 108 + 10 + 19 + 127 + 28 + 64 = 372~g/mol

Detailed skeletal atomic breakdown calculation diagram for Q48
The diagram displays the full multi-cyclic skeletal structure of an antiviral nucleoside molecule featuring explicit iodine and fluorine atomic positions.

Step 1: Final Mass Scaling

Find the mass of 0.1~mol of the sample:

Weight = 0.1 × 372 = 37.2~g = 372 × 10⁻¹~g

Hence, the integer value for the blank box is 372.

Pattern Recognition

When counting atoms in nucleoside structures, remember that each vertex in the ribose sugar ring represents a fully saturated carbon component unless double bonds or heteroatoms are explicitly drawn.

Chapter Mix

Class 12 Chemistry: Biomolecules Class 11 Chemistry: Some Basic Concepts of Chemistry

Q37 jee_main_2025_02_april_morning Amino Acids Properties
Identify the correct statement among the following:
  • A. (1) All naturally occurring amino acids except glycine contain one chiral centre.
  • B. (2) All naturally occurring amino acids are optically active.
  • C. (3) Glutamic acid is the only amino acid that contains a -COOH group at the side chain.
  • D. (4) Amino acid, cysteine easily undergo dimerization due to the presence of free SH group.

Solution

Related Formula

Dimerization of thiol pairs yields a disulfide linkage via an oxidation mechanism:

2R-SH [-H₂] R-S-S-R
Core Logic

Let's review each choice item factually layout-by-row:

  • Option 1 is inaccurate: Isoleucine and threonine contain two distinct chiral centers.
  • Option 2 is inaccurate: Glycine lacks a asymmetric center, rendering it optically inactive.
  • Option 3 is inaccurate: Aspartic acid similarly contains a carboxylic acid functional group along its side chain.
  • Option 4 is correct: Cysteine contains a highly active free functional -SH group that easily dimerizes to form Cystine through a disulfide loop matrix.
Pattern Recognition

Disulfide bridges formed by cysteine play a crucial role in maintaining the tertiary and quaternary structural configurations of complex protein folds.

Chapter Mix

Class 12 Chemistry: Biomolecules

Q28 jee_main_2025_03_april_evening Vitamins Classification
Fat soluble vitamins are: A. Vitamin B₁ B. Vitamin C C. Vitamin E D. Vitamin B₁₂ E. Vitamin K Choose the correct answer from the options given below :
  • A. C & D Only
  • B. A & B Only
  • C. B & C Only
  • D. C & E Only

Solution

Related Formula

Vitamins are classified into two categories based on solubility:

  • Water-soluble: Vitamin B-complex and Vitamin C.
  • Fat-soluble: Vitamins A, D, E, and K.
Core Logic

Categorize each given vitamin:

  • Vitamin B₁ (Thiamine) arrow Water-soluble
  • Vitamin C (Ascorbic acid) arrow Water-soluble
  • Vitamin E (Tocopherol) arrow Fat-soluble
  • Vitamin B₁₂ (Cobalamin) arrow Water-soluble
  • Vitamin K (Phylloquinone) arrow Fat-soluble
Step 1: Select correct options

Only C (Vitamin E) and E (Vitamin K) are fat-soluble. Thus, the correct option is (4).

Pattern Recognition

Use the mnemonic 'ADEK' to remember the fat-soluble vitamins. All other vitamins (mainly B-complex and C) are water-soluble.

Chapter Mix

Class 12 Chemistry: Biomolecules

Q jee_main_2025_07_april_morning Hormones Structure
Thyroxine, the hormone has the structure given below:
Chemical skeletal structure of thyroxine hormone for Q47
The structural formula of Thyroxine shows four iodine atoms attached to the aromatic benzene rings.
The percentage of iodine in thyroxine is ______ %. (nearest integer) (Given molar mass in g mol⁻¹ of C: 12, H: 1, O: 16, N: 14, I: 127)
Numerical Answer. Answer: 65 to 65

Solution

Related Formula
% I = 4 × MIMThyroxine × 100
Core Logic

Let's first determine the molecular formula of Thyroxine from its structure shown in below :

Thyroxine molecular structure highlight for Q47
The structural formula of Thyroxine shows four iodine atoms attached to the aromatic benzene rings.

  • Formula: C₁₅H₁₁O₄NI₄
  • Now, compute the molecular mass:

  • Carbon: 15 × 12 = 180
  • Hydrogen: 11 × 1 = 11
  • Oxygen: 4 × 16 = 64
  • Nitrogen: 1 × 14 = 14
  • Iodine: 4 × 127 = 508
Total Molecular Mass = 180 + 11 + 64 + 14 + 508 = 777 g mol⁻¹

Now, calculate the percentage of Iodine:

% I = (508)/(777) × 100 ≈ 65.38 % ≈ 65 %

Hence, the percentage of iodine in thyroxine is 65.

Pattern Recognition

Thyroxine molecular mass (777) is composed mostly of Iodine (508), making up approximately 508/777 ≈ 65% of its entire mass. Always carefully account for the four phenyl-bound iodines.

Evaluation Rubric / Model Answer

Accurate molecular weight summation leading to 65% nearest integer Iodine composition.

Chapter Mix

Class 12 Chemistry: Biomolecules Class 12 Chemistry: Organic Chemistry - Oxygen containing compounds

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