A toxic compound “A” when reacted with NaCN in aqueous acidic medium yields an edible cooking component and food preservative “B”. “B” is converted to “C” by diborane and can be used as an additive to petrol to reduce emission. “C” upon reaction with oleum at 140^circmathrmC yields an inhalable anesthetic “D”. Identify “A”, “B”, “C” and “D”, respectively.

Solution & Explanation

### Core Logic Let's track the conversions row by row based on the description: 1. Toxic compound **A** is methanol (CH_3OH). Reacting it via acidic NaCN sequences effectively converts it eventually into acetic acid (CH_3COOH), which is an edible cooking component and food preservative (vinegar) **B**. 2. Reduction of acetic acid (**B**) with diborane (B_2H_6) yields ethanol (CH_3CH_2OH) **C**. Ethanol is used as a biofuel additive in petrol. 3. Ethanol (**C**) upon heating with oleum/concentrated sulfuric acid at 140^circmathrmC undergoes intermolecular dehydration to yield diethyl ether (C_2H_5-O-C_2H_5) **D**, which functions as an inhalable anesthetic. ### Step 1: Chemical Reaction Sequence Flow
Chemical flow chart for sequential ether preparation
Chemical flow chart for sequential ether preparation
The full sequential progression corresponds exactly to: textMethanol (A) rightarrow textAcetic Acid (B) rightarrow textEthanol (C) rightarrow textDiethyl ether (D) ### Pattern Recognition Key temperature indicator: Dehydration of ethanol at 140^circmathrmC yields diethyl ether (ether synthesis), whereas 170^circmathrmC yields ethene gas. Combined with the food preservative clue (acetic acid), the sequence locks instantly to option (3). ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 12 Chemistry: Alcohols, Phenols and Ethers

Reference Study Guides

More Alcohols, Phenols and Ethers Previous-Year Questions — Page 3

Q66 jee_main_2024_30_january_evening Preparation of Alcohols
Product A and B formed in the following set of reactions are:
Preparation of Alcohols diagram for Q66 - JEE Main 2024 Evening
The diagram shows a reaction pathway for synthesizing product A and B.
  • A. textA = mathrmCH_2OH text, B = mathrmCH_2OH
  • B. textA = mathrmCH_3OH text, B = mathrmCH_3OH
  • C. textA = mathrmCH_2OH text, B = mathrmCH_3OH
  • D. textA = mathrmCH_3OH text, B = mathrmCH_3OH

Solution

### Core Logic The given substrate is an alkene attached to a benzene ring (styrene derivative). Reaction 1: Acid-catalyzed hydration (H^+ / H_2O) This proceeds via Markovnikov's rule. The proton attacks the alkene to form the most stable carbocation (benzyllic and secondary). Water then attacks this carbocation to yield the alcohol at the substituted position (product A: Ph-CH(OH)-CH_3). Reaction 2: Hydroboration-Oxidation (B_2H_6, then H_2O_2/NaOH) This proceeds via anti-Markovnikov addition of water across the double bond without carbocation rearrangement. The OH group adds to the less substituted carbon atom of the alkene (product B: Ph-CH_2-CH_2-OH).
Reaction pathway for products A and B diagram for Q66 - JEE Main 2024 Evening
The diagram shows a reaction pathway for synthesizing product A and B.
### Pattern Recognition H^+/H_2O = Markovnikov hydration (carbocation intermediate). B_2H_6 / H_2O_2, OH^- = Anti-Markovnikov hydration (concerted, no rearrangement). ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 12 Chemistry: Alcohols Phenols and Ethers Class 11 Chemistry: Hydrocarbons
Q69 jee_main_2024_31_jan_morning Chemical Reactions of Alcohols
Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R: Assertion A: Alcohols react both as nucleophiles and electrophiles. Reason R: Alcohols react with active metals such as sodium, potassium and aluminum to yield corresponding alkoxides and liberate hydrogen. In the light of the above statements, choose the correct answer from the options given below:
  • A. textA is false but R is true.
  • B. textA is true but R is false.
  • C. textBoth A and R are true and R is the correct explanation of A.
  • D. textBoth A and R are true but R is NOT the correct explanation of A.

Solution

### Core Logic Assertion (A) is correct. Alcohols can act as nucleophiles (in reactions involving O-H bond cleavage) and as electrophiles (in reactions involving C-O bond cleavage after protonation). Reason (R) is correct. Alcohols react with active metals to form alkoxides and H_2 gas. However, Reason (R) only explains the acidic nature of the O-H bond (which relates to nucleophilic behavior when broken) but does not explain the electrophilic behavior (C-O cleavage). Thus, (R) is not the correct explanation for (A). ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 12 Chemistry: Alcohols, Phenols and Ethers
Q74 jee_main_2024_31_jan_morning Acidity of Phenols
Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R: Assertion A: pK_a value of phenol is 10.0 while that of ethanol is 15.9. Reason R: Ethanol is stronger acid than phenol. In the light of the above statements, choose the correct answer from the options given below:
  • A. textA is true but R is false.
  • B. textA is false but R is true.
  • C. textBoth A and R are true and R is the correct explanation of A.
  • D. textBoth A and R are true but R is NOT the correct explanation of A.

Solution

### Core Logic Assertion A is true: Phenol has a pK_a of around 10.0, and ethanol has a pK_a of around 15.9. Reason R is false: A lower pK_a value implies higher acidity. Therefore, phenol is a stronger acid than ethanol. This is because the conjugate base of phenol (phenoxide ion) is resonance-stabilized, whereas the ethoxide ion is destabilized by the +I effect of the ethyl group. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 12 Chemistry: Alcohols, Phenols and Ethers

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JEE Physics: Waves (+15.5%) | Electrostatics: Concentric Shells (-29.7%) | Modern Physics: Photoelectric Clones (+34.2%) | Mathematics: Definite Integrals (+18.1%) | Chemistry: Coordination Splitting (-11.4%) | JEE Physics: Waves (+15.5%) | Electrostatics: Concentric Shells (-29.7%) | Modern Physics: Photoelectric Clones (+34.2%) | Mathematics: Definite Integrals (+18.1%) | Chemistry: Coordination Splitting (-11.4%)