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Chemical Bonding and Molecular Structure appeared 42 times across 3 years — 4.9% of Chemistry. This question is from Hybridization and VSEPR Theory.

Year 2026 2025 2024 Total
Questions 12 14 16 42

Two p-block elements X and Y form fluroides of the type EF₃. The fluoride compound XF₃ is a Lewis acid and YF₃ is a Lewis base. The hybridization of the central atoms of XF₃ and YF₃ respectively are

Solution & Explanation

Core Logic

XF₃ acts as a Lewis acid, meaning it is an electron-deficient species capable of accepting an electron pair. A common example from the p-block is BF₃. The central Boron atom has 3 bond pairs and 0 lone pairs. Therefore, its steric number is 3, corresponding to sp² hybridization.

YF₃ acts as a Lewis base, meaning it has an available lone pair to donate. A common example is NF₃. The central Nitrogen atom has 3 bond pairs and 1 lone pair. Its steric number is 4, corresponding to sp³ hybridization.

Step 1: Final Conclusion

The hybridization of X and Y respectively are sp² and sp³.

Pattern Recognition

Electron deficient central atoms (Group 13) form sp² planar molecules. Atoms with a lone pair (Group 15) form sp³ pyramidal molecules.

Chapter Mix

Class 11 Chemistry: Chemical Bonding and Molecular Structure Class 11 Chemistry: p-Block Elements

Reference Study Guides

More Chemical Bonding and Molecular Structure Previous-Year Questions — Page 9

Q77 jee_main_2024_31_jan_morning Molecular Orbital Theory
The linear combination of atomic orbitals to form molecular orbitals takes place only when the combining atomic orbitals A. have the same energy B. have the minimum overlap C. have same symmetry about the molecular axis D. have different symmetry about the molecular axis Choose the most appropriate from the options given below:
  • A. A, B, C only
  • B. A and C only
  • C. B, C, D only
  • D. B and D only

Solution

Core Logic

Conditions for the linear combination of atomic orbitals (LCAO) to form molecular orbitals:

  • The combining atomic orbitals must have the same or nearly the same energy.
  • The combining atomic orbitals must have the same symmetry about the molecular axis.
  • The combining atomic orbitals must overlap to the maximum extent (not minimum).
Chapter Mix

Class 11 Chemistry: Chemical Bonding and Molecular Structure

Q85 jee_main_2024_31_jan_morning Hybridization
The number of species from the following in which the central atom uses sp³ hybrid orbitals in its bonding is NH₃, SO₂, SiO₂, BeCl₂, CO₂, H₂O, CH₄, BF₃
Numerical Answer. Answer: 4 to 4

Solution

Core Logic

Analyzing the hybridization of the central atom in each species:

  • NH₃: 3 bp + 1 lp = 4 electron domains arrow sp³
  • SO₂: 2 bp + 1 lp = 3 electron domains arrow sp²
  • SiO₂: A giant covalent network where each Si is bonded to 4 oxygens tetrahedrally arrow sp³
  • BeCl₂: 2 bp + 0 lp = 2 electron domains arrow sp
  • CO₂: 2 bp + 0 lp = 2 electron domains arrow sp
  • H₂O: 2 bp + 2 lp = 4 electron domains arrow sp³
  • CH₄: 4 bp + 0 lp = 4 electron domains arrow sp³
  • BF₃: 3 bp + 0 lp = 3 electron domains arrow sp²
  • Total species with sp³ hybridization: NH₃, SiO₂, H₂O, CH₄. Total count = 4.

Chapter Mix

Class 11 Chemistry: Chemical Bonding and Molecular Structure

More Chemical Bonding and Molecular Structure Questions — jee_main_2026_22_january_morning

Practice all Chemical Bonding and Molecular Structure previous-year questions →

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