Given below are two statements: Statement I: The correct order in terms of bond dissociation enthalpy is textCl_2 > textBr_2 > textF_2 > textI_2. Statement II: The correct trend in the covalent character of the metal halides is [textSnCl_4 > textSnCl_2], [textPbCl_4 > textPbCl_2] and [textUF_4 > textUF_6] (or similar Fajan's rule trend). In the light of the above statements, choose the correct answer from the options given below:

Solution & Explanation

### Core Logic - Statement I: Bond dissociation energy order for halogens is textCl_2 > textBr_2 > textF_2 > textI_2 due to small size and lone-pair repulsions in fluorine weakening its bond. Statement I is true. - Statement II: According to Fajan's rules, higher charge on cation increases covalent character, so textUF_6 > textUF_4 (higher oxidation state has greater covalent character), making the statement II claim regarding textUF_4 > textUF_6 false. ### Step 1: Final Conclusion Statement I is true but Statement II is false, corresponding to option (1). ### Pattern Recognition Sees: halogen bond dissociation energy anomalies and Fajan's rules for covalent character. Trap: Assuming fluorine has the highest bond dissociation energy among halogens. ### Chapter Mix Class 11 Chemistry: Chemical Bonding and Molecular Structure

Reference Study Guides

More Chemical Bonding and Molecular Structure Questions — jee_main_2026_21_jan_evening

Practice all Chemical Bonding and Molecular Structure previous-year questions →

Rankbit System
JEE Physics: Waves (+15.5%) | Electrostatics: Concentric Shells (-29.7%) | Modern Physics: Photoelectric Clones (+34.2%) | Mathematics: Definite Integrals (+18.1%) | Chemistry: Coordination Splitting (-11.4%) | JEE Physics: Waves (+15.5%) | Electrostatics: Concentric Shells (-29.7%) | Modern Physics: Photoelectric Clones (+34.2%) | Mathematics: Definite Integrals (+18.1%) | Chemistry: Coordination Splitting (-11.4%)