In Dumas' method for estimation of nitrogen, 1mathrm~g$1\mathrm{~g}$ of an organic compound gave 150mathrm~mL$150\mathrm{~mL}$ of nitrogen collected at 300mathrm~K$300\mathrm{~K}$ temperature and 900mathrm~mmHg$900\mathrm{~mmHg}$ pressure. The percentage composition of nitrogen in the compound is _______ %$%$ (nearest integer). (Aqueous tension at 300mathrm~K = 15mathrm~mmHg$300\mathrm{~K} = 15\mathrm{~mmHg}$)

### Related Formula textIntramolecular H-bonding implies textLower boiling point implies textSteam Volatile$$\text{Intramolecular H-bonding} \implies \text{Lower boiling point} \implies \text{Steam Volatile}$$ ### Core Logic Purification via steam distillation requires a high relative vapor pressure at the boiling point of water. Let us assess the isomers : * (A) o-Nitrophenol contains an -mathrmOH$-\mathrm{OH}$ group right next to an -mathrmNO_2$-\mathrm{NO}_2$ group, allowing for strong intramolecular hydrogen bonding. This minimizes external interactions, lowering the boiling point and making it steam volatile . * (B) o-Nitroaniline similarly stabilizes itself via internal intramolecular hydrogen bonding between the amine and nitro components, making it steam volatile . * (C) & (D) The para isomers form extensive intermolecular networks with neighboring molecules, which significantly elevates their boiling points and prevents steam volatility .

Hence, compounds (A) and (B) are steam volatile, matching option (3). ### Pattern Recognition ortho-substituted functional networks form self-contained internal loops through hydrogen bonding, preventing external pairing and maximizing volatility. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Organic Chemistry - Some Basic Principles and Techniques Class 11 Chemistry: Chemical Bonding and Molecular Structure

### Related Formula textSingle bond = 1sigma, quad textDouble bond = 1sigma + 1pi, quad textTriple bond = 1sigma + 2pi$$\text{Single bond} = 1\sigma, \quad \text{Double bond} = 1\sigma + 1\pi, \quad \text{Triple bond} = 1\sigma + 2\pi$$ ### Core Logic Let us map out the complete structural bond geometry of Hex-1,3-dien-5-yne : mathrmH_2C=CH-CH=CH-Cequiv CH$$\mathrm{H_2C=CH-CH=CH-C\equiv CH}$$ Counting the individual bonds : * Carbon-Hydrogen (mathrmC-H$\mathrm{C-H}$) single bonds = 2 + 1 + 1 + 1 + 1 = 6 \, sigma$= 2 + 1 + 1 + 1 + 1 = 6 \, \sigma$ bonds * Carbon-Carbon single, double, and triple linkages: * mathrmC_1=mathrmC_2 ightarrow 1sigma + 1pi$\mathrm{C}_1=\mathrm{C}_2 ightarrow 1\sigma + 1\pi$ * mathrmC_2-mathrmC_3 ightarrow 1sigma$\mathrm{C}_2-\mathrm{C}_3 ightarrow 1\sigma$ * mathrmC_3=mathrmC_4 ightarrow 1sigma + 1pi$\mathrm{C}_3=\mathrm{C}_4 ightarrow 1\sigma + 1\pi$ * mathrmC_4-mathrmC_5 ightarrow 1sigma$\mathrm{C}_4-\mathrm{C}_5 ightarrow 1\sigma$ * mathrmC_5equivmathrmC_6 ightarrow 1sigma + 2pi$\mathrm{C}_5\equiv\mathrm{C}_6 ightarrow 1\sigma + 2\pi$ Total values : textTotal sigma text bonds = 6 + 5 = 11$$\text{Total } \sigma \text{ bonds} = 6 + 5 = 11$$ textTotal pi text bonds = 1 + 1 + 2 = 4$$\text{Total } \pi \text{ bonds} = 1 + 1 + 2 = 4$$ textSum (sigma + pi) = 11 + 4 = 15$$\text{Sum } (\sigma + \pi) = 11 + 4 = 15$$ ### Pattern Recognition Do not skip implicit mathrmC-H$\mathrm{C-H}$ single bonds when scanning skeletal formulas, as each counts as a full sigma$\sigma$ bond. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Organic Chemistry - Some Basic Principles and Techniques

### Core Logic Bond fission in organic chemistry can happen in two ways: 1. Homolytic cleavage: The shared pair of electrons gets distributed equally, leading to free radical formation. 2. Heterolytic cleavage: The shared pair of electrons goes completely to one of the bonded atoms, leading to the formation of positive (cation) and negative (anion) ions. ### Step 1: Match Definition Since ionic reactions involve ions, they inherently proceed through heterolytic bond cleavage where ionic intermediates (carbocations, carbanions, or leaving groups) are formed. ### Pattern Recognition Ionic reactions rightarrow$\rightarrow$ Ions formed rightarrow$\rightarrow$ Heterolytic cleavage. Radical reactions rightarrow$\rightarrow$ Free radicals formed rightarrow$\rightarrow$ Homolytic cleavage. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Organic Chemistry Some Basic Principles and Techniques

### Core Logic Kjeldahl's method is used for the quantitative estimation of Nitrogen in organic compounds. The organic compound is heated with concentrated H_2SO_4$H_2SO_4$ to convert nitrogen into ammonium sulfate. In this digestion step, a catalyst is required to speed up the decomposition and oxidation of the organic matter. ### Step 1: Identify Role of Reagent CuSO_4$CuSO_4$ (or sometimes Mercury/Selenium) is added to the digestion mixture. It acts solely as a catalytic agent to increase the rate of digestion (breakdown of organic material). ### Pattern Recognition In Kjeldahl's digestion: H_2SO_4$H_2SO_4$ = oxidizing agent / reactant, K_2SO_4$K_2SO_4$ = raises boiling point, CuSO_4$CuSO_4$ = catalyst. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Organic Chemistry Some Basic Principles and Techniques

### Core Logic Deactivating groups pull electron density away from the aromatic ring, making it less reactive towards electrophilic substitution. These groups generally have a strong -M (mesomeric/resonance) effect or a very strong -I (inductive) effect without compensating +M. Let's evaluate each group from the image: 1. -CO-CH_3$-CO-CH_3$ (Acetyl group): Has a carbonyl double bond directly attached to the ring. Shows -M and -I effect. rightarrow$\rightarrow$ Deactivating. 2. -OCH_3$-OCH_3$ (Methoxy group): Oxygen has a lone pair. Shows strong +M effect which dominates its -I effect. rightarrow$\rightarrow$ Activating. 3. -NH-CH_3$-NH-CH_3$ (N-Methylamino group): Nitrogen has a lone pair. Shows strong +M effect. rightarrow$\rightarrow$ Activating. 4. -Cequiv N$-C\equiv N$ (Cyano group): Triple bond directly attached, nitrogen is highly electronegative. Shows strong -M and -I effect. rightarrow$\rightarrow$ Deactivating. 5. Wait, looking closely at the solution image for the 5 groups: The groups presented are: (1) -CO-CH_3$-CO-CH_3$ (-M group, deactivating) (2) -OCH_3$-OCH_3$ (+M group, activating) (3) -NH-CH_3$-NH-CH_3$ (+M group, activating) (4) -Cequiv N$-C\equiv N$ (-M group, deactivating) (Wait, the fifth group in the question image is not explicitly named here but the solution labels show 4 groups in the block? Ah, the question image actually has 5 structural parts or the text just lists them. The solution states: "-C=N, -OCH3" and labels (-M group), (+M group). It counts exactly 2 deactivating groups.) Let's analyze the groups labeled as (-M) in the solution: -CO-CH_3$-CO-CH_3$ and -Cequiv N$-C\equiv N$. ### Step 1: Count Deactivating Groups Deactivating groups (-M effect): 1. -CO-CH_3$-CO-CH_3$ 2. -Cequiv N$-C\equiv N$ Total number = 2.

### Pattern Recognition If the atom directly attached to the benzene ring has a multiple bond to a more electronegative atom (like C=O$C=O$, Cequiv N$C\equiv N$, N=O$N=O$, S=O$S=O$), the group is deactivating (-M). ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Organic Chemistry Some Basic Principles and Techniques