Solution
Related Formula
H₂(g) arrow 2H^+(aq) + 2e^- E = E° - (0.059)/(n) [H^+]²PH₂Core Logic
[H^+] = 0.02 M, PH₂ = 2 atm, n = 2 E = 0 - (0.059)/(2) ((0.02)²)/(2) = -0.0295 (2 × 10⁻⁴) E = -0.0295 ( 2 - 4) = -0.0295 (0.3010 - 4) = -0.0295 (-3.699) = +0.109 VStep 1: Final Value
Half cell EMF is +0.109 V.
Pattern Recognition
For oxidation half cell H₂ arrow 2H^+ + 2e^-, Nernst equation uses ratio [H^+]² / PH₂.
Chapter Mix
Class 12 Chemistry: Electrochemistry