Core Logic
The main element of the apatite mineral family (e.g., fluorapatite Ca₅(PO₄)₃F$Ca_{5}(PO_{4})_{3}F$) is Phosphorus (P$P$).
The first four elements of Group 15 are N$N$, P$P$, As$As$, Sb$Sb$. First ionization enthalpy decreases regularly down the group:
IE₁(N) > IE₁(P) > IE₁(As) > IE₁(Sb)$$IE_1(N) > IE_1(P) > IE_1(As) > IE_1(Sb)$$
Sorting the given enthalpy data values in decreasing order:
1402 > 1012 > 947 > 834$$1402 > 1012 > 947 > 834$$
Assigning these to the elements:
- N = 1402 kJ mol⁻¹$N = 1402\text{ kJ mol}^{-1}$
- P = 1012 kJ mol⁻¹$P = 1012\text{ kJ mol}^{-1}$
- As = 947 kJ mol⁻¹$As = 947\text{ kJ mol}^{-1}$
- Sb = 834 kJ mol⁻¹$Sb = 834\text{ kJ mol}^{-1}$
Pattern Recognition
Apatite family = Phosphorus reference. Match the elements down a column directly to a monotonic numerical array.
Chapter Mix
Class 12 Chemistry: p-Block Elements