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p-Block Elements appeared 42 times across 3 years — 4.9% of Chemistry. This question is from Group 15 Elements Trends.

Year 2026 2025 2024 Total
Questions 16 13 13 42

First ionisation enthalpy values of first four group 15 elements are given below. Choose the correct value for the element that is a main component of apatite family: (1) 1012 kJ mol⁻¹ (2) 1402 kJ mol⁻¹ (3) 834 kJ mol⁻¹ (4) 947 kJ mol⁻¹

Solution & Explanation

Core Logic

The main element of the apatite mineral family (e.g., fluorapatite Ca₅(PO₄)₃F) is Phosphorus (P).

The first four elements of Group 15 are N, P, As, Sb. First ionization enthalpy decreases regularly down the group:

IE₁(N) > IE₁(P) > IE₁(As) > IE₁(Sb)

Sorting the given enthalpy data values in decreasing order:

1402 > 1012 > 947 > 834

Assigning these to the elements:

  • N = 1402 kJ mol⁻¹
  • P = 1012 kJ mol⁻¹
  • As = 947 kJ mol⁻¹
  • Sb = 834 kJ mol⁻¹
Pattern Recognition

Apatite family = Phosphorus reference. Match the elements down a column directly to a monotonic numerical array.

Chapter Mix

Class 12 Chemistry: p-Block Elements

Reference Study Guides

More p-Block Elements Previous-Year Questions — Page 9

Q61 jee_main_2024_31_jan_morning Group 18 Elements
Give below are two statements: Statement-I: Noble gases have very high boiling points. Statement-II: Noble gases are monoatomic gases. They are held together by strong dispersion forces. Because of this they are liquefied at very low temperature. Hence, they have very high boiling points. In the light of the above statements, choose the correct answer from the options given below:
  • A. Statement I is false but Statement II is true.
  • B. Both Statement I and Statement II are true.
  • C. Statement I is true but Statement II is false.
  • D. Both Statement I and Statement II are false.

Solution

Core Logic

Statement I and II are False.

Noble gases have low boiling points. Noble gases are held together by weak dispersion forces.

Pattern Recognition

Noble gases are characterized by extremely weak intermolecular forces (London dispersion forces) because they are monoatomic and non-polar, which directly results in very low boiling and melting points.

Chapter Mix

Class 12 Chemistry: The p-Block Elements

Q79 jee_main_2024_31_jan_morning Group 14 Elements
Consider the oxides of group 14 elements SiO₂, GeO₂, SnO₂, PbO₂, CO and GeO. The amphoteric oxides are
  • A. GeO, GeO₂
  • B. SiO₂, GeO₂
  • C. SnO₂, PbO₂
  • D. SnO₂, CO

Solution

Core Logic

In Group 14 elements, the nature of oxides varies down the group: CO is neutral. CO₂ and SiO₂ are acidic. GeO₂ is distinctly acidic. SnO₂ and PbO₂ are amphoteric.

Pattern Recognition

Tin (Sn) and Lead (Pb) mostly form amphoteric oxides (e.g., SnO, SnO₂, PbO, PbO₂), distinguishing them from the acidic oxides of Carbon and Silicon.

Chapter Mix

Class 11 Chemistry: The p-Block Elements

More p-Block Elements Questions — jee_main_2025_29_jan_evening

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