Assume a living cell with 0.9\% (omega/omega) of glucose solution (aqueous). This cell is immersed in another solution having equal mole fraction of glucose and water. (Consider the data upto first decimal place only) The cell will:

Solution & Explanation

### Related Formula Mass percentage from mole fraction calculation: \%text w/w = fracx_1 cdot M_1x_1 cdot M_1 + x_2 cdot M_2 times 100 ### Core Logic Inside the living cell, glucose concentration is 0.9\%text w/w. The surrounding solution has equal mole fractions of glucose and water (x_textglucose = 0.5, x_textwater = 0.5). Let's calculate the mass percentage of the outer solution: - Mass of glucose component = 0.5 times 180 = 90mathrm\ g - Mass of water component = 0.5 times 18 = 9mathrm\ g - Total solution mass = 90 + 9 = 99mathrm\ g ### Step 1: Concentration Determination and Osmosis Profile Outer mass percentage: \%text w/w = frac9099 times 100 approx 90.9\% Because the external environment is highly concentrated (hypertonic) compared to the inner cell (0.9\%), water flows out of the cell via exosmosis, causing the **cell to shrink**. Note: Because the reasoning establishes shrinkage but the quantitative figures in the options are highly mismatched, this question is officially designated as a **Bonus** question. ### Pattern Recognition An equal mole fraction solution of a high-molar-mass solute (glucose, 180mathrm\ g/mol) and a low-molar-mass solvent (water, 18mathrm\ g/mol) is always extremely concentrated by mass. Placing a standard living cell into such a hypertonic solution inevitably causes fluid loss and cellular shrinkage. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 12 Chemistry: Solutions

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Q87 jee_main_2024_31_jan_evening Concentration Terms
The molarity of 1text L orthophosphoric acid (H_3PO_4) having 70\% purity by weight (specific gravity 1.54text g cm^-3) is ________ textM. (Molar mass of H_3PO_4 = 98text g mol^-1)
Numerical Answer. Answer: 11 to 11

Solution

### Related Formula M = frac\% text purity times textdensity times 10textMolar Mass ### Core Logic Specific gravity is numerically equivalent to density in textg/cm^3, so density = 1.54text g/mL. Volume of solution = 1text L = 1000text mL. Mass of solution = textVolume times textDensity = 1000 times 1.54 = 1540text g. ### Step 1: Finding Solute Mass and Molarity Since the purity is 70\% by weight, the mass of H_3PO_4 in the solution is: textMass of H_3PO_4 = 1540 times 0.70 = 1078text g. Moles of H_3PO_4 = frac107898 = 11text moles. Since this is dissolved in 1text L of solution, the Molarity is: M = frac11text moles1text L = 11text M ### Pattern Recognition Shortcut formula directly substitutes the values: M = frac70 times 1.54 times 1098 = frac107898 = 11. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 12 Chemistry: Solutions Class 11 Chemistry: Some Basic Concepts of Chemistry
Q63 jee_main_2024_31_jan_morning Non-Ideal Solutions
Identify the mixture that shows positive deviations from Raoult's Law
  • A. (CH_3)_2CO + C_6H_5NH_2
  • B. CHCl_3 + C_6H_6
  • C. CHCl_3 + (CH_3)_2CO
  • D. (CH_3)_2CO + CS_2

Solution

### Core Logic (CH_3)_2CO + CS_2 exhibits positive deviations from Raoult's Law because the interactions between acetone and carbon disulphide molecules are weaker than the respective pure component interactions. ### Pattern Recognition Mixtures like Acetone + Aniline or Chloroform + Benzene/Acetone form stronger hydrogen bonds after mixing, showing negative deviation. Acetone + CS_2 or Ethanol + Acetone break existing strong interactions, leading to positive deviation. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 12 Chemistry: Solutions

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