| List-I (Saccharides) | List-II (Glycosidic-linkages found) |
|---|---|
| (A) Sucrose | (I) α 1-4 |
| (B) Maltose | (II) α 1-4 and α 1-6 |
| (C) Lactose | (III) α 1 - β 2 |
| (D) Amylopectin | (IV) β 1-4 |
Solution
Related Formula
Glycosidic linkages define the connectivity between monosaccharide units in disaccharides and polysaccharides.
Core Logic
Analyzing each saccharide configuration:
- Sucrose: Formed by α-D-glucose and β-D-fructose via a α 1 - β 2 glycosidic linkage.
- Maltose: Composed of two α-D-glucose units connected by a α 1-4 glycosidic linkage.
- Lactose: Composed of β-D-galactose and β-D-glucose via a β 1-4 glycosidic linkage.
- Amylopectin: A branched polymer of glucose with linear α 1-4 linkages and branching at α 1-6 positions.
Step 1: Final Mapping
Matching pairs lead to: (A)-(III), (B)-(I), (C)-(IV), (D)-(II).
Pattern Recognition
Remember shortcuts for common linkages:
- Sucrose is a non-reducing sugar involving the anomeric carbons of both units (α 1 - β 2).
- Lactose has a β-linkage (β 1-4).
- Amylopectin represents branched starch (α 1-4 and α 1-6).
Chapter Mix
Class 12 Chemistry: Biomolecules