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Some Basic Concepts of Chemistry appeared 30 times across 3 years — 3.5% of Chemistry. This question is from Concentration Terms.

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Questions 8 15 7 30

Fortification of food with iron is done using FeSO₄· 7H₂O. The mass in grams of the FeSO₄· 7H₂O required to achieve 12~ppm of iron in 150~kg of wheat is _______. (Nearest integer) [Given: Molar mass of Fe, S and O respectively are 56, 32 and 16 ~g~mol⁻¹]

Numerical Answer Type:
Enter a numerical value Answer: 9 to 9 +4 marks

Solution & Explanation

Related Formula
ppm = Mass of solute (g)Total mass of solution/mixture (g) × 10⁶
Core Logic

Let the required mass of pure iron be w~g. The total mass of the wheat mixture is 150~kg = 150 × 10³~g. Applying the parts-per-million concentration condition:

12 = (w)/(150 × 10³) × 10⁶ 12 = w × 6.666 w = (12 × 150 × 10³)/(10⁶) = 1.8~g of Iron

Now, determine the molar mass of the complete green vitriol salt crystal template, FeSO₄ · 7H₂O:

M = 56 + 32 + (4 × 16) + (7 × 18) = 56 + 32 + 64 + 126 = 278 ~g~mol⁻¹

Set up a stoichiometric mass balance proportion to find the total salt mass w₁:

Moles of Fe = (1.8)/(56) = (w₁)/(278) w₁ = (1.8 × 278)/(56) = (500.4)/(56) ≈ 8.935~g

Rounding off to the nearest integer value gives 9.

Pattern Recognition

Always convert concentration metrics back to absolute molar mass equivalence values before distributing across full hydrated molecular templates.

Chapter Mix

Class 11 Chemistry: Some Basic Concepts of Chemistry

Reference Study Guides

More Some Basic Concepts of Chemistry Previous-Year Questions — Page 6

Q jee_main_2024_29_january_evening Volumetric Titration and Molarity
If 50 mL of 0.5 M oxalic acid is required to neutralise 25 mL of NaOH solution, the amount of NaOH in 50 mL of given NaOH solution is ________ g.
Numerical Answer. Answer: 4 to 4

Solution

Related Formula
Equivalents of Acid = Equivalents of Base N₁ V₁ = N₂ V₂ (M₁ × n₁) × V₁ = (M₂ × n₂) × V₂
Core Logic

For oxalic acid (H₂C₂O₄), the valence factor (n-factor) is 2. For NaOH, the n-factor is 1. Substituting the values into the normality equivalence expression:

50 × 0.5 × 2 = 25 × MNaOH × 1 50 = 25 × MNaOH MNaOH = 2 M
Step 1: Mass Isolation

To find the mass of NaOH present in 50 mL of this solution:

Mass = Molarity × Volume (in L) × Molar Mass Mass = 2 × ((50)/(1000)) × 40 = 2 × 0.05 × 40 = 4 g
Pattern Recognition

Remember to use the correct n-factor (2) for dibasic oxalic acid during equivalence matching to avoid calculation errors.

Chapter Mix

Class 11 Chemistry: Some Basic Concepts of Chemistry

Q83 jee_main_2024_27_jan_morning Stoichiometry
Mass of methane required to produce 22 g of CO₂ after complete combustion is g. (Given Molar mass in g mol⁻¹: C=12.0, H=1.0, O=16.0)
Numerical Answer. Answer: 8 to 8

Solution

Related Formula

Balanced combustion chemical equation:

CH₄ + 2O₂ arrow CO₂ + 2H₂O Moles = MassMolar Mass
Step 1: Determine moles of product generated
Molar Mass of CO₂ = 12 + (2 × 16) = 44 g mol⁻¹ Moles of CO₂ produced = (22)/(44) = 0.5 moles
Step 2: Relate to input mass via stoichiometry metrics

From the balanced equation, 1 mole of CH₄ produces 1 mole of CO₂.

Required Moles of CH₄ = 0.5 moles Molar Mass of CH₄ = 12 + (4 × 1) = 16 g mol⁻¹ Mass of CH₄ = 0.5 × 16 = 8 g
Pattern Recognition

22 g of CO₂ is exactly half a mole. By stoichiometry ratios, half a mole of methane is needed, which translates to 8 g.

Chapter Mix

Class 11 Chemistry: Some Basic Concepts of Chemistry

Q88 jee_main_2024_30_jan_morning Mole Concept
0.05 cm thick coating of silver is deposited on a plate of 0.05 m² area. The number of silver atoms deposited on plate are ________ × 10²³. (At mass Ag=108, d=7.9 g cm⁻³)
Numerical Answer. Answer: 11 to 11

Solution

Related Formula
Volume = Area × Thickness Mass = Density × Volume Moles = MassMolar Mass Number of Atoms = Moles × NA
Step 1: Calculate Volume of Coating

Area = 0.05 m² = 0.05 × 10⁴ cm² = 500 cm² Thickness = 0.05 cm Volume = 500 cm² × 0.05 cm = 25 cm³

Step 2: Calculate Mass and Moles

Mass = Volume × Density = 25 cm³ × 7.9 g/cm³ = 197.5 g Moles of Ag = (197.5)/(108) = 1.8287 moles

Step 3: Calculate Number of Atoms
Number of Atoms = 1.8287 × 6.022 × 10²³ = 11.01 × 10²³

Rounding to nearest integer, we get 11.

Chapter Mix

Class 11 Chemistry: Some Basic Concepts of Chemistry Class 12 Chemistry: Electrochemistry

Q62 jee_main_2024_31_jan_evening Stoichiometry and Calculations
A sample of CaCO₃ and MgCO₃ weighed 2.21 g is ignited to constant weight of 1.152 g. The composition of mixture is: (Given molar mass in g mol⁻¹ CaCO₃:100, MgCO₃:84)
  • A. 1.187~g~CaCO₃ + 1.023~g~MgCO₃
  • B. 1.023~g~CaCO₃ + 1.023~g~MgCO₃
  • C. 1.187~g~CaCO₃ + 1.187~g~MgCO₃
  • D. 1.023~g~CaCO₃ + 1.187~g~MgCO₃

Solution

Related Formula
CaCO₃(s) Δ CaO(s) + CO₂(g) MgCO₃(s) Δ MgO(s) + CO₂(g)
Core Logic

Let the weight of CaCO₃ be x g. Then, the weight of MgCO₃ = (2.21 - x) g.

Moles of CaCO₃ decomposed = Moles of CaO formed. (x)/(100) = Moles of CaO formed Weight of CaO formed = (x)/(100) × 56

Moles of MgCO₃ decomposed = Moles of MgO formed. ((2.21 - x))/(84) = Moles of MgO formed Weight of MgO formed = (2.21 - x)/(84) × 40

Step 1: Setting up the Equation

The total weight of the residue (CaO + MgO) is given as 1.152 g.

(2.21 - x)/(84) × 40 + (x)/(100) × 56 = 1.152
Step 2: Solving for x
(88.4 - 40x)/(84) + 0.56x = 1.152 1.0523 - 0.4761x + 0.56x = 1.152 0.0839x = 0.0997 x = 1.188 g

So, weight of CaCO₃ ≈ 1.187 g (accounting for rounding) Weight of MgCO₃ = 2.21 - 1.188 = 1.022 g ≈ 1.023 g.

Chapter Mix

Class 11 Chemistry: Some Basic Concepts of Chemistry

Q83 jee_main_2024_31_jan_morning Stoichiometry
Number of moles of methane required to produce 22g CO2(g) after combustion is x × 10⁻² moles. The value of x is
Numerical Answer. Answer: 50 to 50

Solution

Step 1: Stoichiometric Equation
CH4(g) + 2O2(g) arrow CO2(g) + 2H₂O(l)

1 mole of CH₄ produces 1 mole of CO₂.

Step 2: Moles Calculation

Molar mass of CO₂ = 12 + 2(16) = 44 g/mol

nCO₂ = MassMolar mass = (22)/(44) = 0.5 moles

Since 1 mole of CH₄ produces 1 mole of CO₂, the moles of CH₄ required is 0.5 moles.

Step 3: Finding x
0.5 moles = 50 × 10⁻² moles

x = 50

Chapter Mix

Class 11 Chemistry: Some Basic Concepts of Chemistry

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