Identify the correct statements: A. Hydrated salts can be used as primary standard. B. Primary standard should not undergo any reaction with air. C. Reactions of primary standard with another substance should be instantaneous and stoichiometric. D. Primary standard should not be soluble in water. E. Primary standard should have low relative molar mass. Choose the correct answer from the options given below:

Solution & Explanation

### Related Formula textPrimary Standard Criteria: High molar mass, stable in air, completely soluble, stoichiometric reaction. ### Core Logic Statement A: TRUE - Certain stable hydrated salts (e.g. oxalic acid dihydrate) are used as primary standards. Statement B: TRUE - Primary standards must be stable in air and not hygroscopic or oxidized by air. Statement C: TRUE - Reactions must be rapid, complete, and strictly stoichiometric. Statement D: FALSE - Primary standards MUST be highly soluble in water to prepare volumetric standard solutions. Statement E: FALSE - Primary standards should ideally have high relative molar mass to minimize weighing errors. Hence, Statements A, B, and C are correct. ### Pattern Recognition Sees: Primary standard characteristics. Shortcut: Soluble in water (eliminates D) and high molar mass required (eliminates E). ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Some Basic Concepts of Chemistry

Reference Study Guides

More Some Basic Concepts of Chemistry Previous-Year Questions

Q56 jee_main_2026_21_jan_morning Eudiometry
80 mL of a hydrocarbon on mixing with 264 mL of oxygen in a closed U-tube undergoes complete combustion. The residual gases after cooling to 273 K occupy 224 mL. When the system is treated with KOH solution, the volume decreases to 64 mL. The formula of the hydrocarbon is :
  • A. mathrmC_2mathrmH_4
  • B. mathrmC_4mathrmH_10
  • C. mathrmC_2mathrmH_2
  • D. mathrmC_2mathrmH_6

Solution

### Related Formula mathrmC_mathrmxmathrmH_mathrmy(g) + left(mathrmx + fracmathrmy4right)mathrmO_2(g) longrightarrow mathrmxCO_2(g) + fracmathrmy2mathrmH_2mathrmO_(ell) ### Core Logic Let the volume of hydrocarbon be V = 80 mL. Initial volume of O_2 = 264 mL. At 273 K, H_2O is liquid, so its volume is neglected. Volume of CO_2 formed = 80x mL. Volume of O_2 used = 80left(x + fracy4right) mL. Unreacted O_2 = 264 - 80left(x + fracy4right) mL. Total residual volume = V_CO_2 + V_unreacted \ O_2 = 224 mL. 80x + 264 - 80left(x + fracy4right) = 224 264 - frac80y4 = 224 40 = 20y implies y = 2 After treatment with KOH, CO_2 is absorbed. The remaining volume is unreacted O_2, which is 64 mL. 264 - 80left(x + fracy4right) = 64 Substitute y = 2: 264 - 80left(x + frac12right) = 64 264 - 80x - 40 = 64 224 - 80x = 64 80x = 160 implies x = 2 The hydrocarbon is mathrmC_2mathrmH_2. ### Pattern Recognition Volume decrease by KOH indicates the volume of CO_2 produced. V_CO_2 = 224 - 64 = 160 mL. V_HC = 80 mL. So x = frac16080 = 2. Total volume reduction = 264 - 64 = 200 mL (O_2 consumed). O_2 consumed = 80(x + y/4) = 200 implies 2 + y/4 = 2.5 implies y/4 = 0.5 implies y = 2. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Some Basic Concepts of Chemistry
Q57 jee_main_2026_21_jan_morning Stoichiometry and Limiting Reagent
14.0 g of calcium metal is allowed to react with excess HCl at 1.0 atm pressure and 273 K. Which of the following statements is incorrect? [Given : Molar mass in mathrmg \ mol^-1 of Ca–40, Cl–35.5, H–1]
  • A. text0.35 mol of H_2text gas is evolved.
  • B. 7.84 mathrm~Ltext of mathrmH_2text gas is evolved.
  • C. text33.3 g of mathrmCaCl_2text is produced.
  • D. textThe limiting reagent is calcium metal.

Solution

### Related Formula mathrmCa_(mathrms) + 2mathrmHCl_(mathrmg) longrightarrow mathrmCaCl_2(mathrms) + mathrmH_2(mathrmg) ### Core Logic Number of moles of Calcium (n_Ca) = fractextGiven masstextMolar mass = frac14.040 = 0.35 mol. Since HCl is in excess, Calcium is the limiting reagent. From stoichiometry, 1 mole of Ca produces 1 mole of H_2 gas and 1 mole of CaCl_2. Moles of H_2 evolved = 0.35 mol. Volume of H_2 at STP (1 atm, 273 K) = 0.35 times 22.4 L = 7.84 L. Mass of CaCl_2 produced = 0.35 times textMolar mass of CaCl_2 = 0.35 times (40 + 71) = 0.35 times 111 = 38.85 g. Option (3) states 33.3 g of CaCl_2 is produced, which is incorrect. ### Step 1: Final Conclusion Statement (3) is incorrect. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Some Basic Concepts of Chemistry
Q55 jee_main_2026_21_jan_evening Percentage Composition and Stoichiometry
By usual analysis, 1.00g of compound (X) gave 1.79g of magnesium pyrophosphate. The percentage of phosphorus in compound (X) is: (nearest integer) (Given, molar mass in textg mol^-1: textO = 16, textMg = 24, textP = 31)
  • A. (1) \ 50
  • B. (2) \ 30
  • C. (3) \ 20
  • D. (4) \ 40

Solution

### Related Formula \% text of textP = fractextMoles of textMg_2textP_2textO_7 times 2 times 31textMass of compound times 100 ### Core Logic Molar mass of textMg_2textP_2textO_7 = 2(24) + 2(31) + 7(16) = 48 + 62 + 112 = 222 text g/mol. textPercentage of P = fracleft(frac1.79222 times 2 times 31right)1 times 100 = 49.99\% approx 50\% ### Step 1: Final Calculation Rounding to the nearest integer gives 50. ### Pattern Recognition Sees: Gravimetric analysis involving magnesium pyrophosphate. Trap: Forgetting the factor of 2 for phosphorus atoms in textMg_2textP_2textO_7. ### Chapter Mix Class 11 Chemistry: Some Basic Concepts of Chemistry
Q56 jee_main_2026_22_january_morning Stoichiometry and Molar Volume
In the reaction, 2Al(s) + 6HCl(aq) rightarrow 2Al^3+(aq) + 6Cl^-(aq) + 3H_2(g)
  • A. text11.2 L H_2(g) text at STP is produced for every mole of HCl consumed.
  • B. text67.2 L H_2(g) text at STP is produced for every mole of Al that reacts.
  • C. text12 L HCl(aq) is consumed for every 6L H_2(g) text produced.
  • D. text33.6 L H_2(g) text is produced regardless of temperature and pressure for every mole of Al that reacts.

Solution

### Related Formula textVolume of gas at STP = textMoles times 22.4 text L ### Core Logic From the balanced chemical equation: 2Al(s) + 6HCl(aq) rightarrow 2Al^3+(aq) + 6Cl^-(aq) + 3H_2(g) 6 moles of HCl produce 3 moles of H_2. Therefore, 1 mole of HCl produces frac36 = 0.5 moles of H_2. Volume of H_2 produced at STP for 1 mole of HCl: V = 0.5 times 22.4text L = 11.2text L ### Step 1: Check other options Option (2): 2 moles of Al produce 3 moles of H_2. 1 mole Al produces 1.5 moles H_2 = 1.5 times 22.4 = 33.6text L (Incorrect). Option (4) is incorrect because volume depends on temperature and pressure. ### Pattern Recognition Standard stoichiometry. Directly map the mole ratio from the balanced equation to molar volume at standard conditions. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Some Basic Concepts of Chemistry
Q53 jee_main_2026_22_january_evening Limiting Reagent and Stoichiometry
textA + 2textB rightarrow textAB_2 36.0text g of 'A' (Molar mass: 60text g mol^-1) and 56.0text g of 'B' (Molar mass: 80text g mol^-1) are allowed to react. Which of the following statements are correct? (A) 'A' is the limiting reagent (B) 77.0text g of textAB_2 is formed (C) Molar mass of textAB_2 is 140text g mol^-1 (D) 15.0text g of A is left unreacted after the completion of reaction. Choose the correct answer from the options given below:
  • A. C and D only
  • B. A and C only
  • C. B and D only
  • D. A and B only

Solution

### Related Formula textMoles (n) = fractextGiven MasstextMolar Mass textMolar Mass of textAB_2 = M_A + 2 M_B ### Core Logic Step 1: Calculate initial moles: n_A = frac3660 = 0.6text mol n_B = frac5680 = 0.7text mol Step 2: Identify Limiting Reagent (LR): textRatio for A = frac0.61 = 0.6, quad textRatio for B = frac0.72 = 0.35 Since ratio of B is smaller, B is the limiting reagent. Step 3: Evaluate product formed and remaining reactant: textMolar mass of textAB_2 = 60 + 2(80) = 220text g mol^-1 textMoles of textAB_2 text formed = 0.35text mol textMass of textAB_2 text formed = 0.35 times 220 = 77.0text g quad text(Statement B is correct) textMoles of A reacted = 0.35text mol textMoles of A remaining = 0.6 - 0.35 = 0.25text mol textMass of A remaining = 0.25 times 60 = 15.0text g quad text(Statement D is correct) ### Pattern Recognition Sees: Initial masses of reactants in stoichiometric equation. Shortcut: Compare n/textcoefficient to find LR, then compute formed product mass and unreacted mass directly. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Some Basic Concepts of Chemistry

More Some Basic Concepts of Chemistry Questions — jee_main_2026_22_january_evening

Practice all Some Basic Concepts of Chemistry previous-year questions →

Rankbit System
JEE Physics: Waves (+15.5%) | Electrostatics: Concentric Shells (-29.7%) | Modern Physics: Photoelectric Clones (+34.2%) | Mathematics: Definite Integrals (+18.1%) | Chemistry: Coordination Splitting (-11.4%) | JEE Physics: Waves (+15.5%) | Electrostatics: Concentric Shells (-29.7%) | Modern Physics: Photoelectric Clones (+34.2%) | Mathematics: Definite Integrals (+18.1%) | Chemistry: Coordination Splitting (-11.4%)