Among mathrmSO_2, mathrmNF_3, mathrmNH_3, mathrmXeF_2, mathrmClF_3 and mathrmSF_4, the hybridization of the molecule with non-zero dipole moment and highest number of lone-pairs of electrons on the central atom is

Solution & Explanation

### Related Formula Steric Number system equation for identifying electronic configurations: textSteric Number (SN) = frac12[mathrmV + mathrmM - mathrmC + mathrmA] ### Core Logic Let's list parameters using a detailed structural grid:
MoleculeHybridisationDipole MomentLone pair on the central atom
mathrmSO_2mathrmsp^2Non-zero1
mathrmNF_3mathrmsp^3Non-zero1
mathrmNH_3mathrmsp^3Non-zero1
mathrmXeF_2mathrmsp^3mathrmdZero3
mathrmClF_3mathrmsp^3mathrmdNon-zero2
mathrmSF_4mathrmsp^3mathrmdNon-zero1
Comparing items: mathrmXeF_2 has 3 lone pairs but its linear architecture enforces mu = 0. Therefore, mathrmClF_3 has the highest count of lone pairs (2) with a net non-zero asymmetric dipole configuration. ### Step 1: Selection The hybridization of mathrmClF_3 is mathrmsp^3mathrmd. ### Pattern Recognition Watch out for symmetry traps! mathrmXeF_2 contains the absolute maximum lone pairs, but its symmetric planar positioning perfectly cancels out the dipole vectors. Thus, the correct candidate slips down to mathrmClF_3. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Chemical Bonding and Molecular Structure

Reference Study Guides

More Chemical Bonding and Molecular Structure Previous-Year Questions — Page 7

Q85 jee_main_2024_31_jan_morning Hybridization
The number of species from the following in which the central atom uses sp^3 hybrid orbitals in its bonding is NH_3, SO_2, SiO_2, BeCl_2, CO_2, H_2O, CH_4, BF_3
Numerical Answer. Answer: 4 to 4

Solution

### Core Logic Analyzing the hybridization of the central atom in each species: - NH_3: 3 bp + 1 lp = 4 electron domains rightarrow sp^3 - SO_2: 2 bp + 1 lp = 3 electron domains rightarrow sp^2 - SiO_2: A giant covalent network where each Si is bonded to 4 oxygens tetrahedrally rightarrow sp^3 - BeCl_2: 2 bp + 0 lp = 2 electron domains rightarrow sp - CO_2: 2 bp + 0 lp = 2 electron domains rightarrow sp - H_2O: 2 bp + 2 lp = 4 electron domains rightarrow sp^3 - CH_4: 4 bp + 0 lp = 4 electron domains rightarrow sp^3 - BF_3: 3 bp + 0 lp = 3 electron domains rightarrow sp^2 Total species with sp^3 hybridization: NH_3, SiO_2, H_2O, CH_4. Total count = 4. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Chemical Bonding and Molecular Structure

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