Core Logic
Statement I: S₈$S_8$ disproportionates in alkaline medium to give sulphide (S²⁻$S^{2-}$) and thiosulphate (S₂O₃²⁻$S_2O_3^{2-}$). The reaction is:
S₈ + 12OH^- arrow 4S²⁻ + 2S₂O₃²⁻ + 6H₂O$$S_8 + 12OH^- \rightarrow 4S^{2-} + 2S_2O_3^{2-} + 6H_2O$$
This is a correct statement.
Statement II: ClO₄^-$ClO_4^-$ contains chlorine in its highest possible oxidation state of +7$+7$. A species can undergo disproportionation only if the element can exist in both higher and lower oxidation states than the present one. Since chlorine cannot exceed +7$+7$, ClO₄^-$ClO_4^-$ cannot undergo disproportionation.
This is an incorrect statement.
Step 1: Final Conclusion
Statement I is correct, and Statement II is incorrect. Therefore, option (1) is the correct answer.
Chapter Mix
Class 11 Chemistry: Redox Reactions
Class 12 Chemistry: The p-Block Elements