Related Formula
C₁₂H₂₂O₁₁ + H₂O H^+ D-Glucose + D-Fructose$$C_{12}H_{22}O_{11} + H_2O \xrightarrow{H^+} D\text{-Glucose} + D\text{-Fructose}$$
Core Logic
Statement I: Pure sucrose has a specific rotation [α]D = +66.5°$[\alpha]_D = +66.5^{\circ}$, so it is dextrorotatory. Upon hydrolysis, it forms an equimolar mixture of D-glucose and D-fructose. The net specific rotation of the mixture is negative, resulting in laevorotation. (This is called inversion of sugar). Statement I is true.
Statement II: Hydrolysis gives glucose and fructose. The specific rotation of D-glucose is +52.5°$+52.5^{\circ}$ (dextrorotation), while that of D-fructose is -92.4°$-92.4^{\circ}$ (laevorotation). The statement claims that glucose is laevorotatory and fructose is dextrorotatory, which is strictly backward. Therefore, Statement II is false.
Step 1: Final Conclusion
Statement I is true but Statement II is false.
Pattern Recognition
Invert sugar concepts are very common. Always verify which monomer rotates light in which direction. D-fructose is strongly laevorotatory (-92.4°$-92.4^{\circ}$).
Chapter Mix
Class 12 Chemistry: Biomolecules