Rankbit System
JEE Physics: Waves (+15.5%) | Electrostatics: Concentric Shells (-29.7%) | Modern Physics: Photoelectric Clones (+34.2%) | Mathematics: Definite Integrals (+18.1%) | Chemistry: Coordination Splitting (-11.4%) | JEE Physics: Waves (+15.5%) | Electrostatics: Concentric Shells (-29.7%) | Modern Physics: Photoelectric Clones (+34.2%) | Mathematics: Definite Integrals (+18.1%) | Chemistry: Coordination Splitting (-11.4%)

The extra stability of half-filled subshell is due to: (A) Symmetrical distribution of electrons (B) Smaller coulombic repulsion energy (C) The presence of electrons with the same spin in non-degenerate orbitals (D) Larger exchange energy (E) Relatively smaller shielding of electrons by one another Identify the correct statements

Solution & Explanation

### Related Formula textExchange Energy (E) propto K cdot fracn(n-1)2 where n represents the total count of parallel spin electrons within degenerate electronic levels. ### Core Logic The enhanced quantum and physical stability belonging to half-filled and completely filled subshells is driven by explicit mechanisms: 1. **Symmetrical distribution**: Electrons in a half-filled subshell are distributed uniformly across all degenerate spatial orientations, minimizing structural polarization. 2. **Large Exchange Energy**: Parallel spins maximize the permissible quantum exchanges, dropping potential energy configurations significantly. 3. **Smaller Coulombic Repulsion**: Placing single electrons inside separate degenerate orbitals reduces electron-electron proximity repulsions compared to forced pairing. 4. **Smaller Shielding Effects**: Uniform spatial shells provide less mutual shielding, allowing closer nuclear interactions. ### Step 1: Assessing Validity Options Evaluating statement metrics: - Statements (A), (B), (D), and (E) outline accurate chemical factors. [cite: 1008, 1009, 1010, 1011] - Statement (C) incorrectly claims non-degenerate orbitals; half-filled configurations strictly populate *degenerate* subshell levels (like p_x, p_y, p_z). ### Pattern Recognition Stability markers checklist: Symmetry, exchange energy maximization, and decreased coulombic repulsion are the dominant triad explaining half-filled orbital stability (e.g., textCr: 3d^5 4s^1 or textCu: 3d^10 4s^1 anomalies). ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Structure of Atom

Reference Study Guides

More Structure of Atom Previous-Year Questions — Page 4

Q40 2025 Bohr's Model and de-Broglie Wavelength
If a_0 is denoted as the Bohr radius of hydrogen atom, then what is the de-Broglie wavelength ( lambda ) of the electron present in the second orbit of hydrogen atom? [n: any integer]
  • A. frac2mathrma_0mathrmnpi
  • B. frac8pi a_0n
  • C. frac4 pi a0n
  • D. frac4mathrmnpimathrma0

Solution

### Related Formula 2pi r_n = nlambda r_n = a_0 cdot n^2 ### Core Logic According to Bohr's quantization postulate condition coupled with de-Broglie's hypothesis : 2pi r_n = nlambda For the second orbit (n = 2), the radius is: r_2 = a_0 cdot (2)^2 = 4a_0 Substituting into the wave perimeter formula : 2pi (4a_0) = nlambda lambda = frac8pi a_0n This strictly matches option (2). ### Pattern Recognition The circumference of an electron's orbit must encompass an exact integral count of complete standing de-Broglie wave wavelengths. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Structure of Atom

More Structure of Atom Questions — jee_main_2025_07_april_evening

Practice all Structure of Atom previous-year questions →

YOUR FIRST PREP STEP STARTS HERE

We Map Every Repeating Question in Competitive Exams.

Say goodbye to generic mock test fatigue. RankBit uses smart analysis to group past exam questions into their foundational Repeating Question Types. Find chapter weightage, track repeating questions, and score higher with targeted practice.

Select Your Target Exam

Choose an exam track below to find formulas per chapter and patterns.

Syncing Exam Intelligence

Mapping formulas and patterns across all tracks…

PATH A — FULL LENGTH PRACTICE

Full Mock Test Hub

Simulate real NTA exam conditions with fully tracked mocks. Time yourself against past papers.

Under Development
PATH B — TARGETED PRACTICE

Topic-wise Practice Hub

Practice past-year questions one chapter at a time. Pick an exam → subject → chapter and get every PYQ for that topic — pulled together from all past papers — with the chapter's key formulas alongside.

Loading Questions... Browse Topics
Latest from the Blog
View all →

Loading articles...