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Thermodynamics appeared 36 times across 3 years — 4.2% of Physics. This question is from Isothermal Expansion with Non-Linear Spring.

Year 2026 2025 2024 Total
Questions 11 19 6 36

A piston of mass M is hung from a massless spring whose restoring force law goes as F = -kx³, where k is the spring constant of appropriate dimension. The piston separates the vertical chamber into two parts, where the bottom part is filled with 'n' moles of an ideal gas. An external work is done on the gas isothermally (at a constant temperature T) with the help of a heating filament (with negligible volume) mounted in lower part of the chamber, so that the piston goes up from a height L₀ to L₁, the total energy delivered by the filament is (Assume spring to be in its natural length before heating)
Piston connected to spring with gas underneath for Q11
A schematic of a piston of mass M connected to a spring inside a vertical chamber, separating gas at the bottom from vacuum/atmosphere at the top.

Solution & Explanation

Related Formula

First Law of Thermodynamics:

Δ Q = Δ U + Wby gas

Work done by an ideal gas during isothermal expansion:

Wgas = nRTln((V₁)/(V₀)) = nRTln((L₁)/(L₀))

Conservation of Energy (Work-Energy Theorem): Total energy delivered by the heating filament (Wfilament) must equal the total work needed to lift the piston against gravity and compress the non-linear spring.

Core Logic

Since the process is isothermal, the change in internal energy of the ideal gas is zero (Δ U = 0). Hence:

Q = Wgas

By the Work-Energy Theorem for the piston:

Wgas + Wfilament = Δ Ugravity + Δ Uspring

Let's evaluate each term:

  • Increase in gravitational potential energy:
Δ Ugravity = Mg(L₁ - L₀)
  • Increase in spring potential energy:
Uspring = -∫L₀L₁ Frestoring dx = ∫L₀L₁ kx³ dx = (k)/(4)(L₁⁴ - L₀⁴)
Step 1: Finding Total Energy Delivered

Isolating Wfilament (the net external energy delivered to the gas system):

Wfilament = Wgas + Mg(L₁ - L₀) + (k)/(4)(L₁⁴ - L₀⁴)

Since Wgas = nRTln((L₁)/(L₀)):

Wfilament = nRTln((L₁)/(L₀)) + Mg(L₁ - L₀) + (k)/(4)(L₁⁴ - L₀⁴)
Pattern Recognition

Notice how energy conservation instantly frames this complex thermodynamics question. The heating filament's energy simply goes into three distinct stores: the isothermal work of gas expansion, raising the mass against gravity (Mgh), and the potential energy of the spring (integrated from kx³). Keeping this total energy ledger in mind prevents tedious mathematical tangents.

Chapter Mix

Class 11 Physics: Thermodynamics: First Law Class 11 Physics: Work, Energy and Power: Variable Force Integration

More Thermodynamics Previous-Year Questions — Page 3

Q47 jee_main_2026_28_january_evening Work Done in Cyclic Process
A thermodynamic system is taken through the cyclic process ABC as shown in the figure. The total work done by the system during the cycle ABC is ____ J.
Work Done in Cyclic Process diagram for Q47 - JEE Main 2026 Evening
A Pressure-Volume indicator diagram showing a clockwise triangular cycle ABC.
Numerical Answer. Answer: 300 to 300

Solution

Related Formula
Wcycle = Area enclosed by the P-V cycle
Core Logic

In a P-V diagram, the work done in a cyclic process is equal to the area of the enclosed loop. Since the cycle ABC is clockwise (A arrow B arrow C arrow A), the net work done by the system is positive.

Step 1: Calculate the Area

The shape ABC is a right-angled triangle. Base of the triangle = Δ V = VC - VA = 5 - 2 = 3 m³ Height of the triangle = Δ P = PB - PC = 300 - 100 = 200 Pa

Step 2: Compute Work Done
W = (1)/(2) × Base × Height W = (1)/(2) × 3 m³ × 200 Pa W = 3 × 100 = 300 J
Pattern Recognition

Always verify axis units (kPa, atm, Liters, cc) before blindly multiplying area. Here units are cleanly in standard SI (Pa and m³), so 1 Pa · 1 m³ = 1 Joule.

Chapter Mix

Class 11 Physics: Thermodynamics

Q10 jee_main_2025_02_april_evening Adiabatic Process
Identify the characteristics of an adiabatic process in a monoatomic gas. (A) Internal energy is constant. (B) Work done in the process is equal to the change in internal energy. (C) The product of temperature and volume is a constant. (D) The product of pressure and volume is a constant. (E) The work done to change the temperature from T₁ to T₂ is proportional to (T₂ - T₁) Choose the correct answer from the options given below:
  • A. (A), (C), (D) only
  • B. (A), (C), (E) only
  • C. (B), (E) only
  • D. (B), (D) only

Solution

Related Formula
  • First Law of Thermodynamics:
  • dQ = dU + dW

    In an adiabatic process:

dQ = 0 dW = -dU
  • Change in Internal Energy:
dU = n Cv dT = n Cv (T₂ - T₁)
Core Logic

Let's analyze each statement:

  • (A) Internal energy is constant: Incorrect. Since temperature changes during an adiabatic expansion/compression, internal energy (U ∝ T) must change.
  • (B) Work done is equal to the change in internal energy: Correct in magnitude (|dW| = |dU|). By definition, dW = -dU, which correlates the magnitude of work to the change in internal energy.
  • (C) Product of temperature and volume is constant: Incorrect. The adiabatic equation of state is T Vγ-1 = constant.
  • (D) Product of pressure and volume is constant: Incorrect. The relation is P V^γ = constant.
  • (E) Work done is proportional to (T₂ - T₁): Correct. Since dW = -dU = -n Cv (T₂ - T₁), work done is directly proportional to the temperature change (T₂ - T₁).
Step 1: Determine the correct option

Since only statements (B) and (E) are correct, the correct option is (3).

Pattern Recognition

Sees: Characteristics of adiabatic thermodynamic process. Trap: Confusing adiabatic state relations (PV^γ = C, TVγ-1 = C) with isothermal state relations (PV = C, T = C). Shortcut: First law of thermodynamics under dQ=0 strictly enforces |dW| = |dU|, which validates statement B and E immediately.

Chapter Mix

Class 11 Physics: Thermodynamics

Q12 jee_main_2025_02_april_morning Thermodynamic Processes
In an adiabatic process, which of the following statements is true?
  • A. The molar heat capacity is infinite
  • B. Work done by the gas equals the increase in internal energy
  • C. The molar heat capacity is zero
  • D. The internal energy of the gas decreases as the temperature increases

Solution

Related Formula

dQ = n C dT

dQ = 0 (for adiabatic process)
Core Logic

An adiabatic process involves no heat exchange between the system and its surroundings (dQ = 0).

The molar heat capacity C is defined as:

C = (1)/(n)(dQ)/(dT)

Since dQ = 0 while the temperature changes (dT ≠ 0):

C = 0

Thus, the molar heat capacity for any adiabatic process is always zero.

Step 1: Check other options
  • Option (1): Isothermal processes have infinite molar heat capacity (dT = 0).
  • Option (2): From the First Law (dQ = dU + dW dW = -dU), the work done equals the decrease in internal energy.
  • Option (4): The internal energy of an ideal gas (dU = n Cv dT) increases directly as temperature increases.
Step 2: Final Conclusion

The statement 'The molar heat capacity is zero' is true.

Pattern Recognition

Adiabatic = no heat flow (dQ=0). Since molar heat capacity tracks the ratio of heat input to temperature change, C must be 0. Conversely, isothermal has infinite capacity because heat is absorbed without any temperature change (dT=0).

Chapter Mix

Class 11 Physics: Thermodynamics

Q jee_main_2025_03_april_evening Thermodynamic Processes and First Law
An ideal gas exists in a state with pressure P₀, volume V₀. It is isothermally expanded to 4 times of its initial volume (V₀), then isobarically compressed to its original volume. Finally the system is heated isochorically to bring it to its initial state. The amount of heat exchanged in this process is :
  • A. P₀V₀(2ln 2-0.75)
  • B. P₀V₀(ln 2-0.75)
  • C. P₀V₀(ln 2-0.25)
  • D. P₀V₀(2ln 2-0.25)

Solution

Related Formula

For a cyclic thermodynamic process, the net change in internal energy is zero:

Δ Ucyclic = 0

By the First Law of Thermodynamics, the total heat exchanged QT equals the net work done Wₙₑₜ:

QT = Wₙₑₜ = W₁ + W₂ + W₃
Core Logic

The cycle consists of three steps:

  • Isothermal expansion from (P₀, V₀) to volume 4V₀.
  • Isobaric compression to the original volume V₀.
  • Isochoric heating back to the initial state.
  • Thermodynamic Processes and First Law
    Thermodynamic Processes and First Law

Step 1: Work in Isothermal Expansion (W₁)

Initial state: (P₀, V₀). Final state volume: 4V₀.

W₁ = P₀ V₀ ln((4V₀)/(V₀)) = P₀ V₀ ln(4) = 2 P₀ V₀ ln(2)

Also, the pressure at the end of this process is:

P₁ = (P₀ V₀)/(4V₀) = (P₀)/(4)
Step 2: Work in Isobaric Compression (W₂)

The process occurs at constant pressure P = P₁ = P₀/4. The volume goes from 4V₀ back to V₀:

W₂ = P Δ V = (P₀)/(4) (V₀ - 4V₀) = (P₀)/(4) (-3V₀) = -0.75 P₀ V₀
Step 3: Work in Isochoric Heating (W₃)

Since the volume is held constant at V₀, no boundary work is done:

W₃ = 0

Step 4: Total Heat Exchanged (QT)
QT = Wₙₑₜ = W₁ + W₂ + W₃ QT = 2 P₀ V₀ ln(2) - 0.75 P₀ V₀ = P₀ V₀ (2ln(2) - 0.75)
Pattern Recognition

In any cyclic system returning to its initial state, finding total heat is mathematically equivalent to calculating the enclosed area on a P-V diagram. Here, the isobaric step occurs at the lowest expanded pressure, resulting in a simple negative rectangular area correction subtracted from the logarithmic isothermal expansion curve.

Chapter Mix

Class 11 Physics: Thermodynamics

Q jee_main_2025_07_april_morning Work Done in Thermodynamic Processes
An ideal gas has undergone through the cyclic process as shown in the figure. Work done by the gas in the entire cycle is × 10⁻¹ J. (Take π = 3.14 )
Elliptical thermodynamic cycle on PV plane for Q25 - JEE Main 2025 Morning
A cycle plot in which the volume lies in cm^3 (150 to 350) and pressure is in kPa (300 to 500), forming an ellipse.
Numerical Answer. Answer: 314 to 314

Solution

Related Formula

The work done W in a cyclic thermodynamic process is equal to the area enclosed by the loop on a Pressure-Volume (P-V) diagram:

W = Area of Closed Loop

For an ellipse with semi-major axis a and semi-minor axis b:

Area = π a b
Core Logic

Determine the semi-axes of the elliptical cycle on the P-V plane:

  • On the Pressure axis (x-axis):
a = Pmax - Pmin2 = (500 - 300)/(2) ~kPa = 100 ~kPa = 10⁵ ~Pa
  • On the Volume axis (y-axis):
b = Vmax - Vmin2 = (350 - 150)/(2) ~cm³ = 100 ~cm³ = 100 × 10⁻⁶ ~m³ = 10⁻⁴ ~m³
Step 1: Calculate Area

Substitute a and b in standard SI units into the area equation:

W = π a b = 3.14 × (10⁵ ~Pa) × (10⁻⁴ ~m³) W = 3.14 × 10 = 31.4 ~J

Express in terms of × 10⁻¹ ~J:

W = 314 × 10⁻¹ ~J

Thus, the multiplier is 314.

Pattern Recognition

Sees: Circular/elliptical thermodynamic cycle. Shortcut: Work done is always π Δ P Δ V / 4. Simply compute the semi-axes difference 100 ~kPa and 100 ~cm³ and multiply by π directly, keeping tracking of metric prefixes (10³ × 10⁻⁶ = 10⁻³).

Chapter Mix

Class 11 Physics: Thermodynamics

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