Number of isomeric products formed by mono-chlorination of 2-methylbutane in presence of sunlight is ________

Numerical Answer Type:
Enter a numerical value Answer: 6 to 6 +4 marks

Solution & Explanation

### Core Logic The structure of 2-methylbutane is CH_3-CH(CH_3)-CH_2-CH_3. It has four different types of hydrogen atoms, which can be substituted to form structural isomers: 1) 1-chloro-2-methylbutane: Chlorination at terminal CH_3 near branch. Yields a chiral center at C2 (2 enantiomers). 2) 2-chloro-2-methylbutane: Chlorination at the tertiary carbon (1 achiral product). 3) 2-chloro-3-methylbutane: Chlorination at the CH_2 group. Yields a chiral center at C2 (2 enantiomers). 4) 1-chloro-3-methylbutane: Chlorination at the far terminal CH_3. No chiral center (1 achiral product).
Halogenation of Alkanes (Isomers) diagram for Q84 - JEE Main 2024 Evening
Halogenation of Alkanes (Isomers) diagram for Q84 - JEE Main 2024 Evening
### Step 1: Counting Stereoisomers Total isomeric products = 2 (from 1st) + 1 (from 2nd) + 2 (from 3rd) + 1 (from 4th) = 6. ### Pattern Recognition When asked for "isomeric products" in halogenation without specifying "structural isomers", you must count stereoisomers (enantiomers) as well. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Hydrocarbons Class 12 Chemistry: Haloalkanes and Haloarenes

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