Related Formula
fmixture = (n₁ f₁ + n₂ f₂)/(n₁ + n₂)$$f_{\text{mixture}} = \frac{n_1 f_1 + n_2 f_2}{n_1 + n_2}$$
γmixture = 1 + 2fmixture$$\gamma_{\text{mixture}} = 1 + \frac{2}{f_{\text{mixture}}}$$
Core Logic
For a monoatomic gas, degrees of freedom f₁ = 3$f_1 = 3$. Moles n₁ = 3$n_1 = 3$.
For a diatomic gas, degrees of freedom f₂ = 5$f_2 = 5$. Moles n₂ = 2$n_2 = 2$.
We can compute the equivalent degrees of freedom for the mixture using a weighted average.
Step 1: Calculate Equivalent Degrees of Freedom
fmixture = (n₁ f₁ + n₂ f₂)/(n₁ + n₂)$$f_{\text{mixture}} = \frac{n_1 f_1 + n_2 f_2}{n_1 + n_2}$$
fmixture = (3(3) + 2(5))/(3 + 2) = (9 + 10)/(5) = (19)/(5)$$f_{\text{mixture}} = \frac{3(3) + 2(5)}{3 + 2} = \frac{9 + 10}{5} = \frac{19}{5}$$
Step 2: Calculate Adiabatic Exponent
γmixture = 1 + 2fmixture$$\gamma_{\text{mixture}} = 1 + \frac{2}{f_{\text{mixture}}}$$
γmixture = 1 + (2)/((19)/(5)) = 1 + (10)/(19) = (29)/(19) ≈ 1.52$$\gamma_{\text{mixture}} = 1 + \frac{2}{\frac{19}{5}} = 1 + \frac{10}{19} = \frac{29}{19} \approx 1.52$$
Pattern Recognition
Alternatively, you can compute Cv$C_v$ and Cₚ$C_p$ for the mixture: Cv,mix = n₁ Cv1 + n₂ Cv2n₁ + n₂$C_{v,mix} = \frac{n_1 C_{v1} + n_2 C_{v2}}{n_1 + n_2}$, and γmix = Cp,mixCv,mix$\gamma_{mix} = \frac{C_{p,mix}}{C_{v,mix}}$. Both methods yield identical results rapidly.
Chapter Mix
Class 11 Physics: Kinetic Theory of Gases
Class 11 Physics: Thermodynamics