Related Formula
Z = √(2)π d² N √((8RT)/(π M))$$Z = \sqrt{2}\pi d^{2} N \sqrt{\frac{8RT}{\pi M}}$$
where d$d$ is molecular diameter, N$N$ is number density, T$T$ is temperature, and M$M$ is molar mass.
Core Logic
Given that T$T$ and N$N$ are identical for both gases:
Z ∝ d²√(M)$$Z \propto \frac{d^2}{\sqrt{M}}$$
From the problem statement:
dA = (dB)/(2), MA = 4MB$$d_A = \frac{d_B}{2}, \quad M_A = 4M_B$$
Calculating the ratio of collision frequencies:
(ZA)/(ZB) = ((dA)/(dB))² × √((MB)/(MA)) = ((1)/(2))² × √((1)/(4)) = (1)/(4) × (1)/(2) = (1)/(8)$$\frac{Z_A}{Z_B} = \left(\frac{d_A}{d_B}\right)^2 \times \sqrt{\frac{M_B}{M_A}} = \left(\frac{1}{2}\right)^2 \times \sqrt{\frac{1}{4}} = \frac{1}{4} \times \frac{1}{2} = \frac{1}{8}$$
Substituting ZB = 32 × 10⁸ /s$Z_B = 32 \times 10^8 /\mathrm{s}$:
ZA = (32 × 10⁸)/(8) = 4 × 10⁸ /s$$Z_A = \frac{32 \times 10^8}{8} = 4 \times 10^8 /\mathrm{s}$$
Step 1: Final Conclusion
The collision frequency in gas A is 4 × 10⁸ /s$4 \times 10^8 /\mathrm{s}$.
Pattern Recognition
Proportionality check: Z ∝ d² / √(M)$Z \propto d^2 / \sqrt{M}$.
Diameter halved 1/4$\implies 1/4$ factor. Mass quadrupled 1/√(4) = 1/2$\implies 1/\sqrt{4} = 1/2$ factor.
Combined factor = 1/4 × 1/2 = 1/8$= 1/4 \times 1/2 = 1/8$. 32 / 8 = 4$32 / 8 = 4$.
Chapter Mix
Class 11 Physics: Kinetic Theory of Gases