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Equilibrium appeared 36 times across 3 years — 4.2% of Chemistry. This question is from Le Chatelier Principle And Equilibrium Calculation.

Year 2026 2025 2024 Total
Questions 10 18 8 36

Observe the following equilibrium in a 1 L flask. A(g) leftharpoons B(g) At T(K), the equilibrium concentrations of A and B are 0.5 M and 0.375 M respectively. 0.1 moles of A is added into the flask and heated to T(K) to establish the equilibrium again. The new equilibrium concentrations (in M) of A and B are respectively.

Solution & Explanation

Related Formula
Keq = [B]eq[A]eq
Core Logic

Initial equilibrium: A leftharpoons B [A] = 0.5 M, [B] = 0.375 M

Keq = (0.375)/(0.5) = 0.75

Now 0.1 mole of A is added to the 1 L flask. New initial [A] = 0.5 + 0.1 = 0.6 M. Reaction shifts forward: A leftharpoons B Eq: 0.6 - x 0.375 + x

Step 1: Solve for x
Keq = 0.75 = (0.375 + x)/(0.6 - x) 0.75(0.6 - x) = 0.375 + x 0.45 - 0.75x = 0.375 + x

1.75x = 0.075

x = (0.075)/(1.75) = (3)/(70) ≈ 0.043 M
Step 2: Calculate New Concentrations

New concentration of A = 0.6 - 0.043 = 0.557 M New concentration of B = 0.375 + 0.043 = 0.418 M

Pattern Recognition

Le Chatelier addition problems require maintaining Keq constant. Set up ICE table after perturbation, equate to initial Keq.

Chapter Mix

Class 11 Chemistry: Equilibrium

Reference Study Guides

More Equilibrium Previous-Year Questions — Page 8

Q62 jee_main_2024_31_jan_morning Equilibrium Constant
For the given reaction, choose the correct expression of KC from the following :- Fe(aq)³⁺ + SCN(aq)⁻ leftharpoons (FeSCN)(aq)²⁺
  • A. KC = [FeSCN²⁺][Fe³⁺][SCN⁻]
  • B. KC = [Fe³⁺][SCN⁻][FeSCN²⁺]
  • C. KC = [FeSCN²⁺][Fe³⁺]²[SCN⁻]²
  • D. KC = [FeSCN²⁺]²[Fe³⁺][SCN⁻]

Solution

Related Formula
KC = [Products][Reactants]
Core Logic
KC = Products ion conc.Reactants ion conc. KC = [FeSCN²⁺][Fe³⁺][SCN⁻]
Chapter Mix

Class 11 Chemistry: Equilibrium

More Equilibrium Questions — jee_main_2026_28_january_evening

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