The steam volatile compounds among the following are:
Choose the correct answer from the options given below:
Four different disubstituted benzene structures are indexed to show spatial isomer distributions.
A.(B) and (D) only
B.(A) and (C) only
C.(A) and (B) only
D.(A), (B) and (C) only
Solution & Explanation
### Related Formula
textIntramolecular H-bonding implies textLower boiling point implies textSteam Volatile$$\text{Intramolecular H-bonding} \implies \text{Lower boiling point} \implies \text{Steam Volatile}$$
### Core Logic
Purification via steam distillation requires a high relative vapor pressure at the boiling point of water. Let us assess the isomers :
* (A) o-Nitrophenol contains an -mathrmOH$-\mathrm{OH}$ group right next to an -mathrmNO_2$-\mathrm{NO}_2$ group, allowing for strong intramolecular hydrogen bonding. This minimizes external interactions, lowering the boiling point and making it steam volatile .
* (B) o-Nitroaniline similarly stabilizes itself via internal intramolecular hydrogen bonding between the amine and nitro components, making it steam volatile .
* (C) & (D) The para isomers form extensive intermolecular networks with neighboring molecules, which significantly elevates their boiling points and prevents steam volatility .
Four different disubstituted benzene structures are indexed to show spatial isomer distributions.Four different disubstituted benzene structures are indexed to show spatial isomer distributions.
Hence, compounds (A) and (B) are steam volatile, matching option (3).
### Pattern Recognition
ortho-substituted functional networks form self-contained internal loops through hydrogen bonding, preventing external pairing and maximizing volatility.
### Evaluation Rubric / Model Answer
null
### Chapter Mix
Class 11 Chemistry: Organic Chemistry - Some Basic Principles and Techniques
Class 11 Chemistry: Chemical Bonding and Molecular Structure
Four different disubstituted benzene structures are indexed to show spatial isomer distributions.
### Core Logic
The enol form of structure (2) produces a fully conjugated, aromatic ring system (phenol derivative) which provides immense resonance stabilization. Therefore, the equilibrium lies heavily toward the enol form. Four choices depicting structure inputs for keto compounds tautomerizing to enols.
### Pattern Recognition
Look for enol forms that attain aromaticity. Aromatic stabilization overrides typical keto-preference factors.
### Chapter Mix
Class 11 Chemistry: Organic Chemistry - Some Basic Principles and Techniques
### Core Logic
Option (4) is a cyclic secondary aliphatic amine (piperidine derivative) where the nitrogen atom is textsp^3$\text{sp}^3$ hybridized and its lone pair is entirely localized, making it highly available to accept a proton. In contrast, options (1), (2), and (3) have lone pairs involved in resonance with aromatic systems or unsaturated structures. Four different amine ring structures listed as options.
### Pattern Recognition
Localized aliphatic amines are consistently stronger Bronsted bases than aromatic or delocalized analogs.
### Chapter Mix
Class 11 Chemistry: Organic Chemistry - Some Basic Principles and Techniques
### Core Logic
Option (4) features an active methylene group flanked directly between two electron-withdrawing carbonyl groupings. The removal of a proton from this central -textCH_2-$-\text{CH}_2-$ carbon produces a conjugate base that is strongly stabilized via extensive delocalization across both oxygen atoms. Four carbonyl organic structures presented as options.
### Pattern Recognition
Look for hydrogens between two -M$-M$ / -I$-I$ carbonyl complexes rightarrow$\rightarrow$ Active methylene effect.
### Chapter Mix
Class 11 Chemistry: Organic Chemistry - Some Basic Principles and Techniques
Q74jee_main_2024_27_jan_morningClassification of Organic Compounds
Cyclohexene is textquadquad$\text{\quad\quad}$ type of an organic compound.
A. Benzenoid aromatic
B. Benzenoid non-aromatic
C. Acyclic
D. Alicyclic
Solution
### Core Logic
Cyclohexene features an aliphatic carbon ring framework containing an unsaturated double bond but lacks an aromatic sextet ring structure. It belongs to the alicyclic category (aliphatic + cyclic compounds). Cyclohexene chemical ring diagram for Q74 - JEE Main 2024 Morning
### Chapter Mix
Class 11 Chemistry: Organic Chemistry - Some Basic Principles and Techniques
Q77jee_main_2024_27_jan_morningIUPAC Nomenclature
IUPAC name of following compound (P) is:
Substituted cyclohexane molecule labeled as compound P.Substituted cyclohexane molecule labeled as compound P.
A. 1-Ethyl-5, 5-dimethylcyclohexane
B. 3-Ethyl-1,1-dimethylcyclohexane
C. 1-Ethyl-3, 3-dimethylcyclohexane
D. 1,1-Dimethyl-3-ethylcyclohexane
Solution
### Core Logic
Number the ring to give substituents the lowest possible locants. Setting locant 1 at the carbon carrying the two methyl groups provides a locant list of (1,1,3)$(1,1,3)$, whereas setting it at the ethyl-bearing carbon gives (1,3,3)$(1,3,3)$. The set (1,1,3)$(1,1,3)$ wins by the lowest locant rule. Then arrange alphabetically: 3-ethyl precedes 1,1-dimethyl. Hence, the correct systematic tag is 3-Ethyl-1,1-dimethylcyclohexane. Substituted cyclohexane molecule labeled as compound P.
### Pattern Recognition
Lowest locant grouping set takes ultimate priority before checking alphabetical organization rules.
### Chapter Mix
Class 11 Chemistry: Organic Chemistry - Some Basic Principles and Techniques
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