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Given below are two statements : Statement (I) : The radii of isoelectronic species increases in the order: mathrm M g ^ 2 + < mathrm N a ^ + < mathrm F ^ - < mathrm O ^ 2 - Statement (II) : The magnitude of electron gain enthalpy of halogen decreases in the order: mathrm C l > mathrm F > mathrm B r > mathrm I

Solution & Explanation

### Related Formula textIonic Radius propto frac1textNuclear Charge (Z) quad text(for Isoelectronic series) ### Core Logic Evaluating each statement systematically : * Statement (I) is correct: mathrmMg^2+, mathrmNa^+, mathrmF^-, mathrmO^2- all possess exactly 10 electrons (isoelectronic). As the positive nuclear charge decreases (Z = 12 for mathrmMg down to Z = 8 for mathrmO), the nucleus exerts less pull on the electron cloud, causing the ionic radius to increase : mathrmMg^2+ < mathrmNa^+ < mathrmF^- < mathrmO^2- * Statement (II) is correct: Chlorine has a higher electron gain enthalpy magnitude than fluorine due to lower electron-electron repulsion in its larger 3p orbital. The standard halogen trend follows: mathrmCl > mathrmF > mathrmBr > mathrmI Thus, both statements are correct. ### Pattern Recognition For species with the same number of electrons, a higher negative charge always leads to a larger electron cloud radius due to reduced nuclear traction. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Classification of Elements and Periodicity in Properties

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