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An ideal gas undergoes a cyclic transformation starting from the point A and coming back to the same point by tracing the path mathrmAto mathrmBto mathrmC rightarrow mathrmDrightarrow mathrmA as shown in the three cases below.
Thermodynamic cyclic path diagrams for Q33 - JEE Main 2025
The diagram displays three distinct cyclic paths (Case I, Case II, Case III) on volume vs pressure graphs.
Choose the correct option regarding Delta U:

Thermodynamic cyclic path diagrams for Q33 - JEE Main 2025
The diagram displays three distinct cyclic paths (Case I, Case II, Case III) on volume vs pressure graphs.
Thermodynamic cyclic path diagrams for Q33 - JEE Main 2025
The diagram displays three distinct cyclic paths (Case I, Case II, Case III) on volume vs pressure graphs.

Solution & Explanation

### Related Formula For any state function like Internal Energy (U), the cyclic integral over a complete closed loop is identically zero: oint dU = 0 implies Delta U_textcyclic = 0 ### Core Logic Internal energy (U) depends only on the initial and final states of the thermodynamic system, not on the path followed. In all three listed cases, the ideal gas undergoes a complete cyclic path that returns to its original configuration state A. ### Step 1: Final Evaluation Since every transformation begins and ends at point A: Delta U_textCase-I = 0 Delta U_textCase-II = 0 Delta U_textCase-III = 0 Therefore, Delta Utext (Case-I) = Delta Utext (Case-II) = Delta Utext (Case-III). ### Pattern Recognition Do not waste time calculating path areas or values if the question asks for a state function change (Delta U, Delta H, Delta S, Delta G) over a cyclic loop. The answer is instantly zero for all cases! ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Thermodynamics

Reference Study Guides

More Thermodynamics Previous-Year Questions — Page 6

Q47 2025 Hess's Law / Enthalpy of Formation
Consider the following data: Heat of formation of CO_2(g) = -393.5mathrm~kJ~mol^-1 Heat of formation of H_2O(l) = -286.0mathrm~kJ~mol^-1 Heat of combustion of benzene = -3267.0mathrm~kJ~mol^-1 The heat of formation of benzene is ______ mathrmkJ~mol^-1 (Nearest integer).
Numerical Answer. Answer: 48 to 48

Solution

### Related Formula Enthalpy of reaction from enthalpy of formation data: Delta H_textreaction = sum Delta H_f(textProducts) - sum Delta H_f(textReactants) ### Core Logic Write out the balanced thermochemical equation for the combustion of benzene (C_6H_6): C_6H_6(l) + frac152O_2(g) rightarrow 6CO_2(g) + 3H_2O(l) Given parameters: - Delta H_c = -3267.0mathrm\ kJ/mol - Delta H_f[CO_2] = -393.5mathrm\ kJ/mol - Delta H_f[H_2O] = -286.0mathrm\ kJ/mol - Delta H_f[O_2] = 0mathrm\ kJ/mol ### Step 1: Applying Hess's Law Substitute these values into the reaction expression: -3267 = [6(-393.5) + 3(-286.0)] - Delta H_f[C_6H_6] -3267 = [-2361.0 - 858.0] - Delta H_f[C_6H_6] -3267 = -3219.0 - Delta H_f[C_6H_6] Delta H_f[C_6H_6] = -3219.0 + 3267.0 = 48mathrm\ kJ/mol ### Pattern Recognition Always set up products minus reactants when using heat of formation data. Pay close attention to stoichiometric coefficients (multiply CO_2 by 6 and H_2O by 3) to ensure accurate bookkeeping. ### Evaluation Rubric / Model Answer null ### Chapter Mix Class 11 Chemistry: Thermodynamics
Q19 2025 Adiabatic Process
The workdone in an adiabatic change in an ideal gas depends upon only : [cite: 1, 2]
  • A. change in its pressure
  • B. change in its specific heat
  • C. change in its volume
  • D. change in its temperature

Solution

### Related Formula Delta W = -Delta U = -n C_v Delta T ### Core Logic In an adiabatic system, no heat exchange occurs (Q=0). By the first law of thermodynamics, Delta W = -Delta U. Since internal energy U depends explicitly on temperature metrics, the total work output shifts uniquely based on temperature variation Delta T. ### Chapter Mix Class 11 Physics: Thermodynamics

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