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Classification of Elements and Periodicity in Properties appeared 36 times across 3 years — 4.2% of Chemistry. This question is from Ionization Enthalpy.

Year 2026 2025 2024 Total
Questions 9 16 11 36

The successive 5 ionisation energies of an element are 800, 2427, 3658, 25024 and 32824 kJ/mol, respectively. By using the above values predict the group in which the above element is present:

Solution & Explanation

Core Logic

Let's examine the differences between successive ionization energies to find where the largest jump occurs:

  • IE₁ = 800 kJ/mol
  • IE₂ = 2427 kJ/mol
  • IE₃ = 3658 kJ/mol
  • IE₄ = 25024 kJ/mol
  • IE₅ = 32824 kJ/mol
  • Notice the massive, multi-fold jump between IE₃ and IE₄ (3658 arrow 25024 kJ/mol).

    This huge increase indicates that removing the 4th electron requires breaking into a stable, filled core noble gas shell configuration. This means the atom has exactly 3 valence electrons in its outermost shell (ns² np¹), which identifies it as a member of Group 13 (the Boron family).

Pattern Recognition

To find the number of valence electrons, look for the ionization step where the value jumps drastically. The number of relatively low ionization steps before that jump equals the number of valence electrons. Here, 3 low steps arrow 3 valence electrons arrow Group 13.

Chapter Mix

Class 11 Chemistry: Classification of Elements and Periodicity in Properties

Reference Study Guides

More Classification of Elements and Periodicity in Properties Previous-Year Questions — Page 8

Q70 jee_main_2024_31_jan_morning Electron Gain Enthalpy
The correct sequence of electron gain enthalpy of the elements listed below is A. Ar B. Br C. F D. S Choose the most appropriate from the options given below:
  • A. C > B > D > A
  • B. A > D > B > C
  • C. A > D > C > B
  • D. D > C > B > A

Solution

Core Logic

Electron gain enthalpy (ΔegH) values are considered with their signs when ordering from largest to smallest algebraically.

ElementΔegH (kJ/mol)
F-333
S-200
Br-325
Ar+96

Arranging these algebraically from highest to lowest: +96 > -200 > -325 > -333 Thus, Ar > S > Br > F, which corresponds to A > D > B > C.

Pattern Recognition

Noble gases always have positive electron gain enthalpies (highest algebraically). Halogens have highly negative values (lowest algebraically). Fluorine is highly negative, Bromine is slightly less negative. Sulfur sits in between.

Chapter Mix

Class 11 Chemistry: Classification of Elements and Periodicity in Properties

More Classification of Elements and Periodicity in Properties Questions — jee_main_2025_24_jan_evening

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